2-Methylpyridine → 2-(2,2-Dichlorovinyl)-benzyl 2-(4-chlorophenyl)-isovalerate

HRID 64919

反応式

HRID 64919 の反応式
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8]([CH:12]([CH3:14])[CH3:13])[C:9](Cl)=[O:10])=[CH:4][CH:3]=1.N1C=CC=CC=1C.[Cl:22][C:23]([Cl:33])=[CH:24][C:25]1[CH:32]=[CH:31][CH:30]=[CH:29][C:26]=1[CH:27]=[O:28]>C1(C)C=CC=CC=1>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8]([CH:12]([CH3:14])[CH3:13])[C:9]([O:28][CH2:27][C:26]2[CH:29]=[CH:30][CH:31]=[CH:32][C:25]=2[CH:24]=[C:23]([Cl:22])[Cl:33])=[O:10])=[CH:4][CH:3]=1

参加物

5

反応物 3

HCID 79752-MethylpyridineHCID 41780012-(4-Chlorophenyl)-3-methylbutanoyl chlorideHCID 137131312-(2,2-Dichlorovinyl)-benzaldehyde

生成物 1

HCID 137131352-(2,2-Dichlorovinyl)-benzyl 2-(4-chlorophenyl)-isovalerate

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

2.8 g (0.012 mole) of 2-(4-chlorophenyl)-isovaleryl chloride in 50 ml of absolute toluene are introduced into 1.2 g (0.013 mole) of -picoline and 3.2 g (0.015 mole) of 2-(2,2-dichlorovinyl)-benzaldehyde in a conical flask at room temperature, while stirring. After 30 minutes, the mixture is filtered under suction over silica gel, and washing is carried out with toluene.

後処理

  1. filtrationthe mixture is filtered under suction over silica gel
  2. washwashing

出典と根拠

ORDレコード
ord-0f238b4ef3e5448f8833fd83cb856d4f
出典データセット
uspto-grants-1986_09
特許番号
US04611010

関連ノート

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