Dipotassium tetrachloroplatinate → Platinous chloride

HRID 653083

反応式

HRID 653083 の反応式
Cl.Cl.[C:3]1([CH2:9][NH2:10])([CH2:7][NH2:8])[CH2:6][CH2:5][CH2:4]1.C([O-])(=O)C.[Na+].[Cl:16][Pt-2:17](Cl)(Cl)[Cl:18].[K+].[K+]>O>[C:3]1([CH2:9][NH2:10])([CH2:7][NH2:8])[CH2:6][CH2:5][CH2:4]1.[Pt:17]([Cl:18])[Cl:16]

参加物

6

反応物 3

HCID 61440Dipotassium tetrachloroplatinateHCID 517045Sodium AcetateHCID 202036281,1-Bis(aminomethyl)cyclobutane dihydrochloride

生成物 2

HCID 2770Platinous chlorideHCID 4328361,1-Cyclobutanedimethanamine

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

A solution of 1.87 g of the above amine in 30 ml of water was treated with 1.64 g of solid sodium acetate followed by 4.15 g of potassium tetrachloroplatinate. The mixture was stirred overnight and filtered. The filtrate was concentrated, giving as a solid 1,1-cyclobutanedimethanamine, compound with platinum chloride.

後処理

  1. filtrationfiltered
  2. concentrationThe filtrate was concentrated

出典と根拠

ORDレコード
ord-e8ec9817642b46d08a31487737b3a61d
出典データセット
uspto-grants-1987_06
特許番号
US04675336

関連ノート

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