3-Hexenol → 2-Butenoic acid, 2-methyl-, (3Z)-3-hexenyl ester, (2Z)-
反応式
[C:1]([O:7][CH3:8])(=[O:6])/[C:2](=[CH:4]\[CH3:5])/[CH3:3].[CH2:9](O)[CH2:10]/[CH:11]=[CH:12]\[CH2:13]C.C([O-])(=O)CCCCCCCCCCC.C([Sn+2]CCCCCCCC)CCCCCCC.C([O-])(=O)CCCCCCCCCCC>C1(C)C=CC=CC=1>[C:1]([O:7][CH2:8][CH2:9]/[CH:10]=[CH:11]\[CH2:12][CH3:13])(=[O:6])/[C:2](=[CH:4]\[CH3:5])/[CH3:3]参加物
5
実験手順
A mixture of 20.0 g. of methyl angelate, 26.34 g. of (Z)-3-hexenyl alcohol, 100 ml. of toluene and 1.2 g. of dioctyltin laurate was placed in a 300 ml. glass flask, which was equipped with a Soxhlet extractor filled on the top with molecular sieve 4A and a reflux cooler.
後処理
- additionA mixture of 20.0 g
- customglass flask, which was equipped with a Soxhlet extractor
出典と根拠
- ORDレコード
- ord-86d99ad2c96d423794886a4f3cc76510
- 出典データセット
- uspto-grants-1986_09
- 特許番号
- US04613680
反応ノート
読み込み中…