Propylene → HCID 86745998、化合物

HRID 654531

反応式

HRID 654531 の反応式
[CH2:1]=[CH:2][CH3:3].[CH:4]([CH:6]1[CH2:11][CH2:10][CH2:9][CH2:8][CH2:7]1)=[CH2:5].C([Al](CC)CC)C.[H][H]>C(O)CCC.CCCCCCC>[CH:4]([CH:6]1[CH2:11][CH2:10][CH2:9][CH2:8][CH2:7]1)=[CH2:5].[CH2:1]=[CH:2][CH3:3]

参加物

7

反応物 4

HCID 8252PropyleneHCID 12757VinylcyclohexaneHCID 16682930TriethylaluminumHCID 178418361HCID 178418361、化合物

生成物 1

HCID 86745998HCID 86745998、化合物

試薬・触媒・溶媒 2

HCID 2631-Butanol溶媒HCID 8900Heptane溶媒

実験手順

In a stainless steel autoclave (inner volume: 5 l) was performed polymerization of propylene using 1.06 g of the above-described vinylcyclohexane polymerization catalyst, 0.75 g of triethyl aluminium, 0.237 g of methyl p-toluylate and 1,500 ml of n-heptane under the conditions of a pressure of 6 kg/cm2 gauge and a temperature of 70° C. and a hydrogen concentration of 1.5% by volume for 40 minute. After completion of the polymerization, 50 ml of n-butanol was added to stop the polymerization and the resulting polymer slurry was taken out followed by the separation of polymer powder and solvent by filtration. After washing the polymer powder with 500 ml of 1N hydrochloric acid, further washing was performed with methanol until the washings became neutral.

後処理

  1. additionwas added
  2. customthe polymerization
  3. customthe resulting polymer slurry was taken out followed by the separation of polymer powder and solvent by filtration
  4. washAfter washing the polymer powder with 500 ml of 1N hydrochloric acid
  5. washfurther washing

出典と根拠

ORDレコード
ord-f562a86f73b64f26b9e112254ecdb431
出典データセット
uspto-grants-1992_07
特許番号
US05132363

関連ノート

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