3-Chloro-2-methyl-1-propene → Chloro(3-chloro-2-methylpropyl)dimethylsilane
反応式
[CH2:1]([Cl:5])[C:2](=[CH2:4])[CH3:3].[SiH:6]([Cl:9])([CH3:8])[CH3:7]>>[Si:6]([CH2:4][CH:2]([CH2:1][Cl:5])[CH3:3])([CH3:8])([CH3:7])[Cl:9]参加物
3
実験手順
In a 100 ml apparatus, there were combined 30.5 g (0.1 mol) of 92% D3D', 9.1 g (0.1 mol) of methallyl chloride, and 9.5 g (0.1 mol) of Me2SiHCl. Heat was applied to 43° C. and 0.05 ml Pt catalyst solution added, causing an exothermic reaction to 95.5° C. in 26 min, with the heat source removed. Vacuum distillation of the complete reaction yielded 7.82 g (42.3%) of Me2SiClCH2CHMeCH2Cl and 16.89 g (45.3%) of D3D'CH2CHMeCH2Cl. This example shows that neither Me2SiHCl nor D3D' is an effective promoter for reaction of the other with methallyl chloride when used at the equimolar level.
後処理
- temperatureHeat
- customwas applied to 43° C.
- customan exothermic reaction to 95.5° C. in 26 min
- customwith the heat source removed
- distillationVacuum distillation of the complete reaction
出典と根拠
- ORDレコード
- ord-c37ae6ebcdfb4438bca4ec9d069cae98
- 出典データセット
- uspto-grants-1986_09
- 特許番号
- US04614812
反応ノート
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