3-Chloro-2-methyl-1-propene → Chloro(3-chloro-2-methylpropyl)dimethylsilane

HRID 65495

反応式

HRID 65495 の反応式
[SiH:1]([Cl:4])([CH3:3])[CH3:2].[CH2:5]([Cl:9])[C:6](=[CH2:8])[CH3:7]>>[Si:1]([CH2:7][CH:6]([CH2:5][Cl:9])[CH3:8])([CH3:3])([CH3:2])[Cl:4]

参加物

3

反応物 2

HCID 112413-Chloro-2-methyl-1-propeneHCID 66108Chlorodimethylsilane

生成物 1

HCID 86665Chloro(3-chloro-2-methylpropyl)dimethylsilane収率 717.2%

実験手順

In a 100 ml apparatus, there were combined 22.3 g (0.1 mol) of MD'M, 9.5 g (0.01 mol) of Me2SiHCl, and 9.1 g (0.1 mol) of methallyl chloride, followed by 0.015 ml Pt catalyst solution at 50° C. There was an exothermic reaction to 96° C. in 6 min. The complete reaction was vacuum distilled yielding 13.28 g (71.8%) of Me2SiClCH2CHMeCH2Cl and 8.63 g (27.6%) of M2D'CH2CHMeCH2Cl. This example indicates that neither MD'M nor Me2SiHCl is an effective promoter for reaction of the other with methallyl chloride when used at the equimolar level. The yield based on methallyl chloride was 99.4%, indicating very efficient reaction of the olefinic reactant.

後処理

  1. customan exothermic reaction to 96° C. in 6 min
  2. customThe complete reaction
  3. distillationdistilled

出典と根拠

ORDレコード
ord-d15f2fc3708a449485f4047fa7ff44e8
出典データセット
uspto-grants-1986_09
特許番号
US04614812

関連ノート

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