Methyldichlorosilane → Chloro(3-chloro-2-methylpropyl)dimethylsilane

反応式

[CH3:1][SiH:2]([Cl:4])[Cl:3].[SiH:5]([Cl:8])([CH3:7])[CH3:6].[CH2:9]([Cl:13])[C:10](=[CH2:12])[CH3:11]>>[Si:5]([CH2:11][CH:10]([CH2:9][Cl:13])[CH3:12])([CH3:7])([CH3:6])[Cl:8].[CH3:1][Si:2]([CH2:11][CH:10]([CH2:9][Cl:13])[CH3:12])([Cl:4])[Cl:3]

参加物

反応物 3

HCID 6376Methyldichlorosilane

HCID 112413-Chloro-2-methyl-1-propene

HCID 66108Chlorodimethylsilane

生成物 2

HCID 86665Chloro(3-chloro-2-methylpropyl)dimethylsilane収率 54%

HCID 102659Silane, dichloro(3-chloro-2-methylpropyl)methyl-収率 19.6%

実験手順

In a 100 ml apparatus, there were combined 8.6 g (0.75 mol) of MeSiHCl2, 7.1 g (0.075 mol) of Me2SiHCl, and 6.8 g (0.075 mol) of methallyl chloride. Pt catalyst solution (0.01 ml) was added at 32° causing an exothermic reaction to 57° C. and completion in 10 min. Distillation yielded 54.0% of Me2SiClCH2CHMeCH2Cl and 19.6% of MeSiCl2CH2CHMeCH2Cl, indicating that at the equimolar level, neither MeSiHCl2 nor Me2SiHCl is a very effective promoter for reactions of the other with methallyl chloride, in terms of yield, but that reaction rates are increased.