Styrene → Prop-2-enenitrile--ethenylbenzene (1/1)

HRID 659600

反応式

HRID 659600 の反応式
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:9](#[N:12])[CH:10]=[CH2:11].P([O-])([O-])([O-])=O.[Ca+2].P([O-])([O-])([O-])=O.[Ca+2].[Ca+2].C(OOCCCCCCCCCCCC)CCCCCCCCCCC.CC(C(C(C(S)(C)C)(C)C)(C)C)C>CN(C=O)C.O>[CH2:11]=[CH:10][C:9]#[N:12].[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

参加物

8

反応物 5

HCID 7501StyreneHCID 7855AcrylonitrileHCID 24456Tricalcium PhosphateHCID 32793Tert-dodecanethiolHCID 76169Lauryl peroxide

生成物 1

HCID 62696Prop-2-enenitrile--ethenylbenzene (1/1)

試薬・触媒・溶媒 2

HCID 962Water溶媒HCID 6228Dimethylformamide溶媒

実験手順

Seventy (70) parts by mass of styrene, 30 parts by mass of acrylonitrile, 1.0 part by mass of calcium phosphate, 0.03 part by mass of “GAFAC GB520” (trade name, dispersing agent, TOHO Chemical Industry Co.,Ltd.), 0.6 part by mass of laurylperoxide, 1.0 part by mass of t-dodecylmercaptan, and 200 parts by mass of ion-exchanged water were charged in a stainless steel reactor equipped with an agitator. The temperature was elevated to 80° C. and polymerization was carried out for 6 hours to obtain a copolymer having an intrinsic viscosity of 0.6 dl/g (at 20° C. in N,N′-dimethylformamide) with 98% conversion.

後処理

  1. additionwere charged in a stainless steel reactor
  2. customequipped with an agitator
  3. customwas elevated to 80° C.
  4. custompolymerization
  5. customto obtain a copolymer

出典と根拠

ORDレコード
ord-1bd277fcc1224561b39d09c95c8563f6
出典データセット
uspto-grants-2011_12
特許番号
US08080606B2

関連ノート

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