Acetonitrile → HCID 21889441、化合物

HRID 720213ノート

反応式

HRID 720213 の反応式
[CH:1]([C:4]1[C:9]([N+:10]([O-:12])=[O:11])=[C:8]([CH:13]([CH3:15])[CH3:14])[CH:7]=[C:6]([CH:16]([CH3:18])[CH3:17])[C:5]=1[S:19]([OH:22])(=[O:21])=[O:20])([CH3:3])[CH3:2].C(#N)C.[Ag:26]=O>CC(C)=O>[CH:1]([C:4]1[C:9]([N+:10]([O-:12])=[O:11])=[C:8]([CH:13]([CH3:14])[CH3:15])[CH:7]=[C:6]([CH:16]([CH3:18])[CH3:17])[C:5]=1[S:19]([O-:22])(=[O:21])=[O:20])([CH3:2])[CH3:3].[Ag+:26]

参加物

5

反応物 3

HCID 6342AcetonitrileHCID 92152Silver(II) oxideHCID 218894203-Nitro-2,4,6-tri(propan-2-yl)benzene-1-sulfonic acid

生成物 1

HCID 21889441HCID 21889441、化合物

試薬・触媒・溶媒 1

HCID 180Acetone溶媒

実験手順

Into a flask was charged 20 parts by 2,4,6-triisopropyl-3-nitrobenzenesulfonic acid, 80 parts of acetonitrile and 40 parts of acetone, and the mixture was stirred at room temperature for 16 hours. To this was added 7.46 parts of silver oxide and the mixture was stirred for 16 hours at room temperature. The resulting mixture was filtrated and concentrated to obtain 23.68 parts of silver 2,4,6-triisopropyl-3-nitrobenzenesulfonate.

後処理

  1. stirringthe mixture was stirred for 16 hours at room temperature
  2. filtrationThe resulting mixture was filtrated
  3. concentrationconcentrated

出典と根拠

ORDレコード
ord-b6723cc8ef694f04952780b5ed70cd0d
出典データセット
uspto-grants-2006_11
特許番号
US07135268B2

反応ノート

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