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Styrene → Prop-2-enenitrile--ethenylbenzene (1/1)

HRID 747394
ノート
印刷プレビュー

反応式

HRID 747394 の反応式
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:9](#[N:12])[CH:10]=[CH2:11].C(OS(C1C=CC=CC=1)(=O)=O)CCCCCCCCCCC.P([O-])([O-])([O-])=O.[Ca+2].P([O-])([O-])([O-])=O.[Ca+2].[Ca+2]>O>[CH2:11]=[CH:10][C:9]#[N:12].[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1
参加物反応条件実験手順後処理出典と根拠反応ノート

参加物

6

反応物 4

HCID 7501StyreneHCID 7855AcrylonitrileHCID 15900Dodecyl benzenesulfonateHCID 24456Tricalcium Phosphate

生成物 1

HCID 62696Prop-2-enenitrile--ethenylbenzene (1/1)

試薬・触媒・溶媒 1

HCID 962Water溶媒

反応条件

温度
85 °C

実験手順

A copolymer resin composed of styrene and acrylonitrile was prepared by suspension polymerization as follows. Two hundred parts by weight of water, 0.02 part by weight of dodecylbenzenesulfonate, and 1 part by weight of calcium phosphate were charged in an 8-L polymerization apparatus. After removal of oxygen by proper nitrogen substitution with stirring, the mixture was heated to 85° C. In the mixture was added 75 parts by weight of styrene, 25 parts by weight of acrylonitrile, and 0.8 part by weight of benzoyl peroxide at the same time, and the resulting mixture was stirred for five hours. To the resulting mixture was further added 0.8 part by weight of benzoyl peroxide, and the resulting mixture was stirred for five hours to terminate the reaction. A styrene-acrylonitrile copolymer resin was obtained by dehydration. The refraction index was 1.57.

後処理

  1. customwas prepared by suspension polymerization
  2. customAfter removal of oxygen by proper nitrogen substitution
  3. additionIn the mixture was added 75 parts by weight of styrene, 25 parts by weight of acrylonitrile, and 0.8 part by weight of benzoyl peroxide at the same time
  4. stirringthe resulting mixture was stirred for five hours
  5. additionTo the resulting mixture was further added 0.8 part by weight of benzoyl peroxide
  6. stirringthe resulting mixture was stirred for five hours
  7. customto terminate
  8. customthe reaction

出典と根拠

ORDレコード
ord-9e8a1ecdb7c448088d379fd20accd19d
出典データセット
uspto-grants-2008_07
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US07396876B2

反応ノート

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