Iodoethane → Ethyl(triphenylmethyl)amine

HRID 80320

反応式

HRID 80320 の反応式
[C:1]1([C:7]([NH2:20])([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.I[CH2:22][CH3:23]>C(#N)C>[C:1]1([C:7]([C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)([C:14]2[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=2)[NH:20][CH2:22][CH3:23])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

参加物

4

反応物 2

HCID 6340IodoethaneHCID 138598Tritylamine

生成物 1

HCID 4447360Ethyl(triphenylmethyl)amine収率 28%

試薬・触媒・溶媒 1

HCID 6342Acetonitrile溶媒

実験手順

Triphenylmethylamine (1.00 g, 3.86 mmol) (Wako Pure Chemical Industries, Ltd.) and iodoethane (1.50 g, 9.62 mmol) (Wako Pure Chemical Industries, Ltd.) were dissolved in acetonitrile (5 mL) (Wako Pure Chemical Industries, Ltd.), and the mixture was left to stand still at room temperature for 3 days. The solvent was distilled off under reduced pressure, and the residue was subjected to silica gel column chromatography (chloroform (Wako Pure Chemical Industries, Ltd.) as an eluent), to thereby obtain the title compound (0.31 g, 28% yield).

後処理

  1. waitthe mixture was left
  2. distillationThe solvent was distilled off under reduced pressure

出典と根拠

ORDレコード
ord-b13daa3783284fc5acaee76552dcdb91
出典データセット
uspto-grants-2014_09
特許番号
US08846012B2

関連ノート

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