Acetone → HCID 86664979、化合物

HRID 83952

反応式

HRID 83952 の反応式
O.CC(C)=O.[C:6]([O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])(=[O:9])[CH:7]=[CH2:8].C=C1CCOC1=O.C([O-])(=O)CCCCCCCCCCCCCCCCC.[Na+].S(OOS([O-])(=O)=O)([O-])(=O)=O.[Na+].[Na+]>>[CH2:14]=[C:13]1[CH2:12][CH2:11][O:10][C:6]1=[O:9].[C:6]([O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])(=[O:9])[CH:7]=[CH2:8]

参加物

7

反応物 6

HCID 180AcetoneHCID 962WaterHCID 62552Stearyl acrylateHCID 62655Sodium PersulfateHCID 68352alpha-Methylene butyrolactoneHCID 2724691Sodium Stearate

生成物 1

HCID 86664979HCID 86664979、化合物

反応条件

温度
60 °C

実験手順

To a high-pressure reactor with a magnetic stirrer is charged 31.50 g (1.75 mol) water, 13.50 g (0.232 mol) acetone, 25.0 g (7.70×10−2 mol) octadecyl acrylate, 25.0 g (0.255 mol) α-methylene-γ-butyrolactone, 1.25 g (4.08×10−3 mol) sodium stearate, and 0.13 g (5.46×10−4 mol) sodium persulfate. Two freeze-pump-thaw cycles using liquid nitrogen sufficiently degass the reaction medium prior to sealing the reactor and heating to 60° C. The reaction is stirred for 16 hours at 60° C. before cooling to room temperature and drying under vacuum at elevated temperature for isolation.

後処理

  1. customsufficiently degass the reaction medium
  2. temperaturebefore cooling to room temperature
  3. customdrying under vacuum at elevated temperature for isolation

出典と根拠

ORDレコード
ord-0ab276d882e44ad1b14ab99621658f7b
出典データセット
uspto-grants-2014_09
特許番号
US08846817B2

関連ノート

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