1-Dodecanethiol → Ethyl Acrylate

HRID 847415

反応式

HRID 847415 の反応式
[CH2:1](S)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].CCCC[CH2:18][C:19]([C:23]([O:25]OC(C)(C)C)=[O:24])([CH2:21]C)[CH3:20]>C1(C)C=CC=CC=1>[C:23]([O:25][CH2:1][CH3:2])(=[O:24])[CH:19]=[CH2:21].[C:23]([O:25][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])(=[O:24])[C:19]([CH3:20])=[CH2:18]

参加物

5

反応物 2

HCID 81951-DodecanethiolHCID 71359725Tert-butyl 2-ethyl-2-methylheptaneperoxoate

生成物 2

HCID 8821Ethyl AcrylateHCID 18510Decyl methacrylate

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

350 g of toluene, 135 g of ethyl acrylate, and 15 g of n-decyl methacrylate were polymerized with stirring in a reaction flask at 50°-60° C. under argon with 0.3 g of dodecyl mercaptan as a regulator and 2 g of t-butyl perneodecanoate as initiator. After about 30 minutes of reaction, the mixture was precipitated in methanol and the polymer was dried under vacuum.

後処理

  1. customAfter about 30 minutes of reaction
  2. customthe mixture was precipitated in methanol
  3. customthe polymer was dried under vacuum

出典と根拠

ORDレコード
ord-c2b49c75adc9482d84cd3eef32fdd950
出典データセット
uspto-grants-1992_08
特許番号
US05141993

関連ノート

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