Barium nitrate → HCID 86587836、化合物

HRID 856868

反応式

HRID 856868 の反応式
[N+]([O-])([O-])=O.[Ba+2:5].[N+]([O-])([O-])=O.[CH2:10]([C:12]1[C:22]([C:23]([CH3:26])([CH3:25])[CH3:24])=[C:21]([OH:27])[C:20]([C:28]([CH3:31])([CH3:30])[CH3:29])=[CH:19][C:13]=1[CH2:14][P:15](=[O:18])([O-:17])[O-:16])[CH3:11].[Na+].[Na+]>>[CH2:10]([C:12]1[C:22]([C:23]([CH3:25])([CH3:24])[CH3:26])=[C:21]([OH:27])[C:20]([C:28]([CH3:29])([CH3:31])[CH3:30])=[CH:19][C:13]=1[CH2:14][P:15](=[O:16])([O-:18])[O-:17])[CH3:11].[CH2:10]([C:12]1[C:22]([C:23]([CH3:25])([CH3:24])[CH3:26])=[C:21]([OH:27])[C:20]([C:28]([CH3:29])([CH3:31])[CH3:30])=[CH:19][C:13]=1[CH2:14][P:15](=[O:16])([O-:18])[O-:17])[CH3:11].[Ba+2:5].[Ba+2:5]

参加物

3

反応物 2

HCID 24798Barium nitrateHCID 86587835Sodium (o-ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate)

生成物 1

HCID 86587836HCID 86587836、化合物

実験手順

5 ml aqueous solution of 392 mg (1.5 mmol) barium nitrate was added dropwise to 7.5 ml aqueous solution of 1 g (2.85 mmol) sodium (o-ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate) (phosphorus compound C described above) at room temperature under stirring. After the mixture was stirred for 1 hour, the precipitates were separated by filtration, washed with water and dried to give barium bis(o-ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate), 508 mg (45%).

後処理

  1. stirringAfter the mixture was stirred for 1 hour
  2. customthe precipitates were separated by filtration
  3. washwashed with water
  4. customdried

出典と根拠

ORDレコード
ord-09e335155be044908b5cd50c70a075a6
出典データセット
uspto-grants-2006_12
特許番号
US07144614B2

関連ノート

読み込み中…