Oxalyl chloride → Acetyl chloride, (benzoyloxy)-

HRID 868190ノート

反応式

HRID 868190 の反応式
[C:1]([O:9][CH2:10][C:11]([OH:13])=O)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C(Cl)(=O)C([Cl:17])=O>C(Cl)(Cl)Cl>[C:1]([O:9][CH2:10][C:11]([Cl:17])=[O:13])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

参加物

4

反応物 2

HCID 65578Oxalyl chloride2 回HCID 12647149HCID 12647149、化合物

生成物 1

HCID 10888895Acetyl chloride, (benzoyloxy)-

試薬・触媒・溶媒 1

HCID 6212Chloroform溶媒

実験手順

4.1 g (0.023 m) Benzoyloxy acetic acid (as synthesized in Example XIII) was combined with 2.96 ml (4.3 g, 0.032 m) oxalyl chloride in 50 ml petroleum ether. This was stirred under a CaSO4 drying tube for 5 hrs., at which time 2.0 ml more oxalyl chloride and 50 ml chloroform were added. The reaction was stirred overnight.

後処理

  1. stirringThe reaction was stirred overnight

出典と根拠

ORDレコード
ord-9f193701636d40df9f6068968c6d3028
出典データセット
uspto-grants-1988_10
特許番号
US04778618

反応ノート

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