Cyanuric chloride → s-Triazine, 2-chloro-4,6-bis(diallylamino)-

HRID 877850

反応式

HRID 877850 の反応式
C(=O)([O-])[O-].[Na+].[Na+].[N:7]1[C:14](Cl)=[N:13][C:11]([Cl:12])=[N:10][C:8]=1Cl.[CH2:16]([NH:19][CH2:20][CH:21]=[CH2:22])[CH:17]=[CH2:18].[OH-].[Na+]>O1CCOCC1>[CH2:16]([N:19]([CH2:20][CH:21]=[CH2:22])[C:14]1[N:7]=[C:8]([N:19]([CH2:20][CH:21]=[CH2:22])[CH2:16][CH:17]=[CH2:18])[N:10]=[C:11]([Cl:12])[N:13]=1)[CH:17]=[CH2:18]

参加物

6

反応物 4

HCID 7954Cyanuric chlorideHCID 10340Sodium CarbonateHCID 14798Sodium HydroxideHCID 31279Diallylamine

生成物 1

HCID 95021s-Triazine, 2-chloro-4,6-bis(diallylamino)-収率 90%

試薬・触媒・溶媒 1

HCID 312751,4-Dioxane溶媒

反応条件

温度
60 °C

実験手順

After 21.2 g (0.20 mol) of sodium carbonate and 20.0 g (0.10 mol) of cyanuric chloride were added and dissolved into 140 g of 1,4-dioxane, 19.8 g (0.20 mol) of diallylamine was gradually added thereinto and further, 8.4 g (0.20 mol) of caustic soda was added thereinto. By generating the heat of reaction, the temperature of reaction solution was raised to about 60° C. and the reaction was continued at the temperature for 2 hours. Thereafter, the reaction mixture was cooled and filtered to remove the sodium chloride generated as the byproduct. The obtained filtrate was distilled under reduced pressure to recover the solvent. Therefore, 34 g (0.09 mol) of 4,6-bis(diallylamino)-2-chloro-1,3,5-triazine was obtained.

後処理

  1. additionwas gradually added
  2. temperatureheat of reaction
  3. customthe temperature of reaction solution
  4. temperatureThereafter, the reaction mixture was cooled
  5. filtrationfiltered
  6. customto remove the sodium chloride
  7. distillationThe obtained filtrate was distilled under reduced pressure
  8. customto recover the solvent

出典と根拠

ORDレコード
ord-96b5833f261949a9b95f072bfe81da03
出典データセット
uspto-grants-2015_03
特許番号
US08987383B2

関連ノート

読み込み中…