2,3-Dinitrophenol → Sodium dinitrophenolate
反応式
[N+:1]([C:4]1[C:5]([N+:11]([O-:13])=[O:12])=[C:6]([OH:10])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].[H-].[Na+:15]>C(Cl)Cl.C1COCC1>[N+:1]([C:4]1[C:5]([N+:11]([O-:13])=[O:12])=[C:6]([O-:10])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].[Na+:15]参加物
5
実験手順
A commercially available dinitrophenol (10.0 g, 54.3 mmol) was dissolved in 250 mL of methylenechloride, and water was removed on anhydrous magnesium sulfate. Solvent was removed by filtration under the reduced pressure. After the anhydrous dinitrophenol (10.0 g, 54.3 mmol) was dissolved in anhydrous THF (300 mL), NaH (0.782 g, 32.6 mmol) was added slowly. After all NaH was added, the solution was stirred for 3 hrs. Solvent was removed under reduced pressure to obtain 60 mol % sodium dinitrophenolate.
後処理
- customwater was removed on anhydrous magnesium sulfate
- customSolvent was removed by filtration under the reduced pressure
- customSolvent was removed under reduced pressure
出典と根拠
- ORDレコード
- ord-e9899c6861a0442297c0e52cecc1a07a
- 出典データセット
- uspto-grants-2015_03
- 特許番号
- US08987411B2
反応ノート
読み込み中…