Acetic Acid → HCID 75985013、化合物
反応式
Br[CH2:2][C:3]([O:11][CH3:12])=[CH:4][C:5](=[O:10])[C:6]([Cl:9])([Cl:8])[Cl:7].[C:13]([O-:16])(=[O:15])[CH3:14].[K+].C(O)(=O)C>[Br-].C([N+](CCCC)(CCCC)CCCC)CCC.C(#N)C>[C:13]([O:16][CH2:2][C:3]([O:11][CH3:12])=[CH:4][C:5](=[O:10])[C:6]([Cl:9])([Cl:8])[Cl:7])(=[O:15])[CH3:14]参加物
6
実験手順
29.6 g (0.1 mol) of 5-bromo-1,1,1-trichloro-4-methoxypent-3-en-2-one, 17 g of potassium acetate, 5 g of tetrabutylammonium bromide and 8 g of acetic acid were stirred in 300 ml of acetonitrile at 40° C. for 16 h. The mixture was concentrated under reduced pressure, and water was added to the residue. The product was extracted with ethyl acetate, the organic phase was washed with water and the solvent was removed fully under reduced pressure.
後処理
- concentrationThe mixture was concentrated under reduced pressure, and water
- additionwas added to the residue
- extractionThe product was extracted with ethyl acetate
- washthe organic phase was washed with water
- customthe solvent was removed fully under reduced pressure
出典と根拠
- ORDレコード
- ord-6997653a992545bf94ed3d2618fd6555
- 出典データセット
- uspto-grants-2012_08
- 特許番号
- US08242313B2
反応ノート
読み込み中…