Z-3-(1,3-dioxan-2-yl)-1-(2-pyridyl)-1-propene → 1-(1,3-Dioxan-2-yl)-3-(2-pyridyl)propane
反応式
[O:1]1[CH2:6][CH2:5][CH2:4][O:3][CH:2]1[CH2:7]/[CH:8]=[CH:9]\[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][N:11]=1>[Pd]>[O:1]1[CH2:6][CH2:5][CH2:4][O:3][CH:2]1[CH2:7][CH2:8][CH2:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][N:11]=1参加物
3
実験手順
Through a suspension of 800 mg (4.2 mmol) of olefin 149 and 100 mg of 10% palladium on carbon was bubbled a steady stream of hydrogen gas for a period of 10 min. The reaction mixture was then filtered through celite and concentrated to give 805 mg of the acetal 150 as a colorless oil. 1H NMR consistent with structure.
後処理
- customwas bubbled a steady stream of hydrogen gas for a period of 10 min
- filtrationThe reaction mixture was then filtered through celite and
- concentrationconcentrated
出典と根拠
- ORDレコード
- ord-600c0203d0174eabae949b47eb4ee810
- 出典データセット
- uspto-grants-1998_03
- 特許番号
- US05723459
反応ノート
読み込み中…