N-Benzylideneaniline → N-(Phenylmethylene)-3-(trimethoxysilyl)-1-propanamine

HRID 890848ノート

反応式

HRID 890848 の反応式
[CH:1](=[N:8][C:9]1C=CC=[CH:11][CH:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.NCCC[Si:19]([O:24][CH3:25])([O:22][CH3:23])[O:20][CH3:21].[SiH4]>C1(C)C(C)=CC=CC=1>[C:2]1([CH:1]=[N:8][CH2:9][CH2:10][CH2:11][Si:19]([O:24][CH3:25])([O:22][CH3:23])[O:20][CH3:21])[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

参加物

5

反応物 3

HCID 10858N-BenzylideneanilineHCID 23953SilaneHCID 83756Aminopropyltrimethoxysilane

生成物 1

HCID 105543N-(Phenylmethylene)-3-(trimethoxysilyl)-1-propanamine

試薬・触媒・溶媒 1

HCID 7237O-Xylene溶媒

反応条件

温度
90 °C

実験手順

25 grams (0.138 moles) of N-benzylidene aniline [cas no. 538-51-2, from TCI America] was combined with 24.7 grams (0.138 moles) of gamma-aminopropyltrimethoxysilane [cas no. 13822-56-5, Silquest A-1110 Silane from Crompton Corporation] and 100 grams of xylene. The resulting slurry was warmed to 90° C. for one hour before a vacuum of 20 mm Hg was applied. Distillation of the xylene and aniline resulted in 36 grams (98%) of N-benzylidene aminopropyltrimethoxysilane [cas no. 67674-55-9] by GC analysis.

後処理

  1. distillationDistillation of the xylene and aniline
  2. customresulted in 36 grams (98%) of N-benzylidene aminopropyltrimethoxysilane [cas no

出典と根拠

ORDレコード
ord-f36fbff332df47769964876f6c3f4a53
出典データセット
uspto-grants-2006_02
特許番号
US06998499B2

反応ノート

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