Methacrylic Acid → Iso-butyl methacrylate methyl methacrylate methacrylic acid

HRID 894647

反応式

HRID 894647 の反応式
[C:1]([O:6][CH2:7][CH:8]([CH3:10])[CH3:9])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:11]([O:16][CH3:17])(=[O:15])[C:12]([CH3:14])=[CH2:13].[C:18]([OH:23])(=[O:22])[C:19]([CH3:21])=[CH2:20].C(S)CCCCCCCCCCC>C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>[C:1]([O:6][CH2:7][CH:8]([CH3:10])[CH3:9])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:11]([O:16][CH3:17])(=[O:15])[C:12]([CH3:14])=[CH2:13].[C:18]([OH:23])(=[O:22])[C:19]([CH3:21])=[CH2:20]

参加物

6

反応物 4

HCID 4093Methacrylic AcidHCID 6658Methyl MethacrylateHCID 7352Isobutyl MethacrylateHCID 81951-Dodecanethiol

生成物 1

HCID 86737946Iso-butyl methacrylate methyl methacrylate methacrylic acid収率 500.9%

試薬・触媒・溶媒 1

HCID 7187Benzoyl Peroxide触媒

実験手順

By the same method and under the same reaction conditions as in Reference Example 4, the dispersing medium was changed from kerosene to ISOPAR-E (an alkane-type solvent, made by Esso Corporation, U.S.A.), and 78.5 g of iso-butyl methacrylate, 15 g of methyl methacrylate, 5.6 g of methacrylic acid (the mole ratio of the three monomers being 5.5:1.5:3), 1 g of benzoyl peroxide and 1 ml of n-dodecyl mercaptan were reacted in 350 ml of the dispersing medium to afford 107 g of iso-butyl methacrylate-methyl methacrylate-methacrylic acid copolymer. Yield 90%. Acid value 169.6. [η]MC25°C. =0.232.

後処理

  1. customBy the same method and under the same reaction conditions as in Reference Example 4
  2. customwere reacted in 350 ml of the dispersing medium

出典と根拠

ORDレコード
ord-f81f27d3da454f028b9473e120c9feca
出典データセット
uspto-grants-1981_08
特許番号
US04284707

関連ノート

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