Azide → 1-Amino-3-acetoxy acetone

HRID 903195

反応式

HRID 903195 の反応式
[N:1]([CH2:4][C:5]([CH2:7][O:8][C:9](=[O:11])[CH3:10])=[O:6])=[N+]=[N-].[N-]=[N+]=[N-]>C(OC(=O)C)C.[Pd]>[NH2:1][CH2:4][C:5]([CH2:7][O:8][C:9](=[O:11])[CH3:10])=[O:6]

参加物

5

反応物 2

HCID 33558AzideHCID 144347801-Azido-3-acetoxyacetone

生成物 1

HCID 221655021-Amino-3-acetoxy acetone

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 8857Ethyl Acetate溶媒

実験手順

1-Azido-3-acetoxyacetone (15.7 g.) is dissolved in ethylacetate (200 ml.). The 10% palladium on carbon catalyst (1.0 g.) is added; the mixture is reduced under hydrogen at atmospheric pressure until the infrared spectrum of an aliquot indicates the absence of the azide. The catalyst is filtered off and the filtrate is evaporated to afford 1-amino-3-acetoxy acetone.

後処理

  1. filtrationThe catalyst is filtered off
  2. customthe filtrate is evaporated

出典と根拠

ORDレコード
ord-44403b84da5b4bf499d6bc0f5f0501bb
出典データセット
uspto-grants-1980_10
特許番号
US04226866

関連ノート

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