Diethylamine → N,N-Diethyl-2-isopropyl-5-methylcyclohexanecarboxamide

HRID 903315

反応式

HRID 903315 の反応式
[CH:1]1([CH3:13])[CH2:6][CH2:5][CH:4]([CH:7]([CH3:9])[CH3:8])[CH:3]([C:10]([OH:12])=O)[CH2:2]1.S(Cl)(Cl)=O.C1(C)CCC(C(C)C)C(C(Cl)=O)C1.[CH2:31]([NH:33][CH2:34][CH3:35])[CH3:32].[OH-].[Na+]>>[CH2:31]([N:33]([CH2:34][CH3:35])[C:10]([CH:3]1[CH:4]([CH:7]([CH3:8])[CH3:9])[CH2:5][CH2:6][CH:1]([CH3:13])[CH2:2]1)=[O:12])[CH3:32]

参加物

6

反応物 5

HCID 8021DiethylamineHCID 14798Sodium HydroxideHCID 24386Thionyl ChlorideHCID 97896p-Menthane-3-carboxylic acidHCID 13734319Cyclohexanecarbonyl chloride, 5-methyl-2-(1-methylethyl)-

生成物 1

HCID 93591N,N-Diethyl-2-isopropyl-5-methylcyclohexanecarboxamide

実験手順

Following the procedure of Example 5, p-menthane-3-carboxylic acid (1.84 g.) was reacted with thionyl chloride and the p-menth-3-oyl chloride then reacted with diethylamine (0.74 g.) in the presence of sodium hydroxide (0.4 g.). The product N,N-diethyl-p-menthane-3-carboxamide was recovered.

後処理

  1. customThe product N,N-diethyl-p-menthane-3-carboxamide was recovered

出典と根拠

ORDレコード
ord-55af27376aad4328a0e398514800ad87
出典データセット
uspto-grants-1980_10
特許番号
US04226988

関連ノート

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