反応式
CS(C)=O.[CH:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.[OH-:11].[Na+].[I-].C[S+](C)(C)=O.[CH:19](O)([CH3:21])[CH3:20]>O>[CH3:20][CH:19]([C:5]12[CH2:10][CH:9]1[C:8](=[O:11])[CH2:7][CH2:6]2)[CH3:21]参加物
7
実験手順
25 ml of DMSO, 35 ml of benzene, 25 ml of isopropyl alcohol, 3.1 g (25 mM) of CP, 2.4 g (30 mM) of 50% aqueous sodium hydroxide and 5 ml of water were added to 6.9 g (31.25 mM) of trimethylsulfoxonium iodide and the reaction was carried out at room temperature for 5 hours. Then, the treatments were carried out as described in Example 8. 2.6 g (76% yield) of crude product were produced, from which1.45 g (42 % yield) of sabina ketone were obtained by distillation.
後処理
- custom2.6 g (76% yield) of crude product were produced, from which1
出典と根拠
- ORDレコード
- ord-f188c799d94b41fb894a66beaaba8e2c
- 出典データセット
- uspto-grants-1979_07
- 特許番号
- US04162258
関連ノート
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