2-Methyl-1-pentanol → Magnesium 2-methyl-1-pentyloxide

HRID 980026

反応式

HRID 980026 の反応式
[CH3:1][CH:2]([CH2:5][CH2:6][CH3:7])[CH2:3][OH:4].[CH2:8]([Li])CCC.C([Mg:17]C(CC)C)CCC.CC[CH2:24][CH2:25][CH2:26][CH2:27][CH3:28]>C1CCCCC1>[CH3:1][CH:2]([CH2:5][CH2:6][CH3:7])[CH2:3][O:4][CH2:8][CH:25]([CH3:24])[CH2:26][CH2:27][CH3:28].[Mg:17]

参加物

6

反応物 4

HCID 77452-Methyl-1-pentanolHCID 8900Heptane2 回HCID 178418339ButyllithiumHCID 178448199HCID 178448199、化合物

生成物 1

HCID 86741193Magnesium 2-methyl-1-pentyloxide

試薬・触媒・溶媒 1

HCID 8078Cyclohexane溶媒

実験手順

To 10 ml of a solution of 4.33 ml of 2-methyl-1-pentanol in heptane there is added 0.4 ml of 1.91 Molar n-butyllithium in cyclohexane. To the cloudy mixture, there is added, slowly and with good mixing, 15 ml of a 1.036 Molar solution of n-butyl-sec-butylmagnesium in heptane. A clear, colorless, viscous solution of magnesium 2-methyl-1-pentyloxide is obtained.

後処理

  1. additionTo the cloudy mixture, there is added

出典と根拠

ORDレコード
ord-13920a553d2d4184aef9eb05f8cdcda1
出典データセット
uspto-grants-1987_01
特許番号
US04634786

関連ノート

読み込み中…