Hydrogen Peroxide → 6-Hydroxy-2-naphthoic acid
反応式
O(C([C:6]1[CH:7]=[C:8]2[C:13](=[CH:14][CH:15]=1)[CH:12]=[C:11]([C:16]([OH:18])=[O:17])[CH:10]=[CH:9]2)(C)C)O.[OH:19]C(C1C=C2C(=CC=1)C=C(C(O)=O)C=C2)(C)C.OO.Cl(O)(=O)(=O)=O>C(#N)C>[OH:19][C:6]1[CH:7]=[C:8]2[C:13](=[CH:14][CH:15]=1)[CH:12]=[C:11]([C:16]([OH:18])=[O:17])[CH:10]=[CH:9]2参加物
6
実験手順
The thus obtained white microcrystals consisting of 6-(2-hydroperoxy-2-propyl)naphthalene-2-carboxylic acid and 6-(2-hydroxy-2-propyl)naphthalene-2-carboxylic acid were reacted in acetonitrile at 50° C. for 30 minutes in the presence of hydrogen peroxide and perchloric acid. Thus, the two compounds were subjected to acid decomposition to form 6-hydroxynaphthalene-2-carboxylic acid almost quantitatively.
出典と根拠
- ORDレコード
- ord-1fab9ee774c44d32b15dfecee500a8f5
- 出典データセット
- uspto-grants-1987_01
- 特許番号
- US04638087
反応ノート
読み込み中…