Water → HCID 19824186、化合物

HRID 981375

反応式

HRID 981375 の反応式
[OH2:1].[C:2]([C:6]1[CH:11]=[C:10]([N:12]=O)[CH:9]=[C:8]([C:14]([CH3:17])([CH3:16])[CH3:15])[C:7]=1[OH:18])([CH3:5])([CH3:4])[CH3:3].ClCCl.[H][H].[CH3:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29]>[Pd]>[OH:18][C:7]1[C:6]([C:2]([CH3:5])([CH3:4])[CH3:3])=[CH:11][C:10]([NH:12][C:24](=[O:1])[CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:3][CH2:2][CH2:6][CH2:7][CH2:8][CH3:9])=[CH:9][C:8]=1[C:14]([CH3:17])([CH3:16])[CH3:15]

参加物

7

反応物 5

HCID 962WaterHCID 6344DichloromethaneHCID 8058HexaneHCID 70383Phenol, 2,6-bis(1,1-dimethylethyl)-4-nitroso-HCID 178418361HCID 178418361、化合物2 回

生成物 1

HCID 19824186HCID 19824186、化合物

試薬・触媒・溶媒 1

HCID 23938Palladium触媒

実験手順

A 2 liter Parr bomb was charged with 210.5 g of 44.6% water wet (0.5 mole, pure, dry) 2,6-di-tert-butyl-4-nitrosophenol, 2.0 g of 5% Pd/C catalyst, 300 ml dichloromethane and 400 ml hexane. The nitrogen purged system was pressurized to 50 psi with hydrogen and the rate of hydrogen uptake noted. Hydrogenation was completed within one hour.

出典と根拠

ORDレコード
ord-89e4a46da6b64ab080f7764d88a2ecde
出典データセット
uspto-grants-1991_02
特許番号
US04990671

関連ノート

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