Trimethylsilane → 1-(2-Hydroxy-2-methylpropoxy)4-[3-(trimethylsilyl)propoxy]-2,2,6,6-tetramethylpiperidine

HRID 989535ノート

反応式

HRID 989535 の反応式
[CH2:1]([O:4][CH:5]1[CH2:10][C:9]([CH3:12])([CH3:11])[N:8]([O:13][CH2:14][C:15]([OH:18])([CH3:17])[CH3:16])[C:7]([CH3:20])([CH3:19])[CH2:6]1)[CH:2]=[CH2:3].[CH3:21][SiH:22]([CH3:24])[CH3:23]>C(O)(C)C.[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl>[OH:18][C:15]([CH3:17])([CH3:16])[CH2:14][O:13][N:8]1[C:7]([CH3:20])([CH3:19])[CH2:6][CH:5]([O:4][CH2:1][CH2:2][CH2:3][Si:22]([CH3:24])([CH3:23])[CH3:21])[CH2:10][C:9]1([CH3:12])[CH3:11]

参加物

5

反応物 2

HCID 70435TrimethylsilaneHCID 120843114-Allyloxy-1-(2-hydroxy-2-methylpropoxy)-2,2,6,6-tetramethylpiperidine

生成物 1

HCID 120843091-(2-Hydroxy-2-methylpropoxy)4-[3-(trimethylsilyl)propoxy]-2,2,6,6-tetramethylpiperidine

試薬・触媒・溶媒 2

HCID 61859Chloroplatinic acid触媒HCID 3776Isopropanol溶媒

実験手順

The title compound is prepared by reacting the compound prepared in Example 17 with trimethylsilane and hydrogen hexachloroplatinate(IV) in isopropyl alcohol.

出典と根拠

ORDレコード
ord-19dc09ebec584110925fadb02f15cb6d
出典データセット
uspto-grants-2003_10
特許番号
US06638997B2

反応ノート

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