Acetic Acid → 1-Nitroadamantane
反応式
[CH:1]12[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH2:2]1)[CH2:8]2.[OH:11][N:12]1C(=O)C2=CC=CC=C2C1=O.C(O)(=[O:25])C>>[N+:12]([C:1]12[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH2:2]1)[CH2:8]2)([O-:11])=[O:25]参加物
4
実験手順
Into a flask, 1 mmole of adamantane, 0.1 mmole of N-hydroxyphthalimide and 6 ml of acetic acid were added to mix. The flask was purged by nitrogen monoxide NO (about 1L) and oxygen O2 (about 1L), and then the mixture was reacted for 20 hours at 110° C. with stirring. The reaction products were analyzed by gas chromatography, and, as a result, the conversion of adamantane was 90%, and 1-nitroadamantane (yield 64%) and 1,3-dinitroadamantane (yield 12%) were formed.
後処理
- additionto mix
- customThe flask was purged by nitrogen monoxide NO (about 1L) and oxygen O2 (about 1L)
- customthe mixture was reacted for 20 hours at 110° C.
出典と根拠
- ORDレコード
- ord-aec03bee9da5464ca1e458d8bae2b610
- 出典データセット
- uspto-grants-2002_10
- 特許番号
- US06468487B1
反応ノート
読み込み中…