Acetic Acid → 1-Nitroadamantane

HRID 992149

反応式

HRID 992149 の反応式
[CH:1]12[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH2:2]1)[CH2:8]2.[OH:11][N:12]1C(=O)C2=CC=CC=C2C1=O.C(O)(=[O:25])C>>[N+:12]([C:1]12[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH2:2]1)[CH2:8]2)([O-:11])=[O:25]

参加物

4

反応物 3

HCID 176Acetic AcidHCID 9238Adamantane2 回HCID 10665N-Hydroxyphthalimide

生成物 1

HCID 641651-Nitroadamantane収率 64%

実験手順

Into a flask, 1 mmole of adamantane, 0.1 mmole of N-hydroxyphthalimide and 6 ml of acetic acid were added to mix. The flask was purged by nitrogen monoxide NO (about 1L) and oxygen O2 (about 1L), and then the mixture was reacted for 20 hours at 110° C. with stirring. The reaction products were analyzed by gas chromatography, and, as a result, the conversion of adamantane was 90%, and 1-nitroadamantane (yield 64%) and 1,3-dinitroadamantane (yield 12%) were formed.

後処理

  1. additionto mix
  2. customThe flask was purged by nitrogen monoxide NO (about 1L) and oxygen O2 (about 1L)
  3. customthe mixture was reacted for 20 hours at 110° C.

出典と根拠

ORDレコード
ord-aec03bee9da5464ca1e458d8bae2b610
出典データセット
uspto-grants-2002_10
特許番号
US06468487B1

関連ノート

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