기본 정보
- CAS
12011-54-0- 표준 SMILES
B12B3B4B1C234- InChIKey
INAHAJYZKVIDIZ-UHFFFAOYSA-N- 분자식
- CB4
- 평균 분자량
- 55.3 g/mol
- 단동위원소 질량
- 56.0372216
개요
See also: Boron carbide (10B4C) (annotation moved to).
이름 및 식별자
- 우선 이름
- Boron carbide
- IUPAC
- 2,3,4,5-tetraboratetracyclo[2.1.0.01,3.02,5]pentane
- 현지명
- 탄화 붕소
- 영어명
- Boron carbide
- 분자식
- CB4
- 분자량
- 55.25
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
12011-54-0、12069-32-8、12316-49-3、60063-34-5- PubChem CID
- 123279
- DTXSID
DTXSID4051615- UNII
- T5V24LJ508
- EC Number
- 234-565-1、235-111-5、235-582-7、262-041-2
물성
구조 계산 물성
- 극성 표면적
- 0 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 0
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 5
- 형식 전하
- 0
- 복잡도
- 106
실험 및 물리화학적 성질
SpringerMaterials Properties
phonon wavenumber
dielectric constant
Physical Description
Large Crystals; Dry Powder
Black shiny solid; [Merck Index] Black odorless powder; Insoluble in water; [Alfa Aesar MSDS]
물리화학적 성질
- 녹는점
- 2450 °C · 2450°C
- 끓는 점
- 3500 °C · 3500°C
- 밀도
- 2.51 g/mL · 2.51 g/mL at 25 °C (lit.)
- 저장 조건
- 2 · 2-8°C
- 용해도
- 2 O, · insoluble in H2O, acid solutions
- 물리적 상태
- 가루
- 색상
- 검은색
- Specific Gravity
- 2.51 · 2.51
- 수용성
- 물에 불용성.
- Merck
- 14 · 14,1344
- 안정성
- 안정적인. 산화제와 호환되지 않습니다. 가연성이 아닙니다.
- InChI
- 1S/CB4/c1-2-4-5-3-1
- InChIKey
- NOJMLSPGQSYAIT-UHFFFAOYSA-N
- SMILES
- B1=BB=C=B1
- NIST
- Boron carbide(12069-32-8)
- EPA
- Boron carbide (B4C) (12069-32-8)
화학적 성질
hard, black, shiny crystal(s), -325 mesh with 99.5% purity; rhomb; hardness 9.3 Mohs; less brittle than most ceramics; does not burn in oxygen flame; used as an abrasive; Knoop hardness ~27GPa; produced by reducing B2O3 with carbon at 1400°C–2300°C; used in crucible form as a container for molten salts except molten caustic and as a 99.5% pure sputtering target for producing semiconductor and wear-resistant films [KIR78] [HAW93] [MER06] [CER91]
안전 및 규제
GHS 분류
GHS Classification
This chemical does not meet GHS hazard criteria for 77.8% (144 of 185) of all reports.
Danger
H360 (19.5%): May damage fertility or the unborn child [Danger Reproductive toxicity]
P203, P280, P318, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 185 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Not Classified
유해성 정보
Regulatory Information
Chemical: Boron carbide (B4C)
Chemical: Boron carbide
Boron carbide (B4C) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Boron carbide (B4C) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
REACH registered substance: Boron carbide (EC: 235-111-5)
Other Safety Information
IMAP assessments - Boron carbide: Environment tier I assessment
IMAP assessments - Boron carbide (B4C): Environment tier I assessment
Hazard Classes and Categories
Repr. 1B (19.5%)
Not Classified
안전 및 보호
Protective Action Criteria (PAC)
2.5 [mg/m3]
27 [mg/m3]
160 [mg/m3]
안전 데이터
- wgk
- 3
- tsca
- TSCA listed
- rtecs
- ED7420000
- HS 번호
- 28499010
- risk_code
- 20
- hazard_code
- Xn
- safety_code
- 22-36/37/39-38
- 기존화학 물질
- KE-03527
- 스토리지 클래스
- 11 - Combustible Solids
화학 및 산업
용도 및 제조
Uses
Used as an abrasive and to make chemical-resistant ceramics and wear-resistant tools; [Merck Index] Also used in nuclear control rods and aircraft composites; [Hawley]
Metal Machining [Category: Heat or Machine]
General Manufacturing Information
All Other Basic Inorganic Chemical Manufacturing
Boron carbide (B4C): ACTIVE
응용 분야
개요Sodium tetraborate decahydrate/borax (anhydrous) is a clear, colorless or pale yellow hygroscopic substance with a faint odor of detergent. It is stable and is incompatible with powdered metalsand slightly soluble in water. It is extensively used in the industrial manufacturing of metallurgical fluxes, fiberglass, ceramics, fertilizers, enamels, heat-resistant glass (e.g., Pyrex), and other chemicals. It decomposes on heating or on burning producing toxic fumes including sodium oxide, reacts with strong oxidants, and in fire gives off irritating or toxic fumes (or gases).
용도Boron carbide (B4C) is a hard, black crystal that is used as an abrasive powder and as an additive to strengthen composite parts in aircraft.
제조 방법
Boron carbide is prepared by reduction of boric oxide either with carbon or with magnesium in presence of carbon in an electric furnace at a temperature above 1,400°C. When magnesium is used, the reaction may be carried out in a graphite furnace and the magnesium byproducts are removed by treatment with acid.
상·하류 제품 정보
상류 원료
하류 제품
공급사100 곳
추가 설명
정의boron carbide: A black solid, B4C,soluble only in fused alkali; it is extremelyhard, over 9 on Mohs’scale; rhombohedral; r.d. 2.52; m.p.2350°C; b.p. >3500°C. Boron carbideis manufactured by the reduction ofboric oxide with petroleum coke inan electric furnace. It is used largelyas an abrasive, but objects can alsobe fabricated using high-temperaturepowder metallurgy. Boron nitride isalso used as a neutron absorber becauseof its high proportion ofboron–10.
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