1,2,3,6-Tetrahydropyridine (HCID 12750)

개요

1,2,3,6-tetrahydropyridine appears as a colorless liquid. Insoluble in water. Floats on water. Vapors heavier than air. Used to make other chemicals.

이름 및 식별자

우선 이름: 1,2,3,6-Tetrahydropyridine
IUPAC: 1,2,3,6-tetrahydropyridine
현지명: 1,2,3,6-테트라하이드로피리딘
영어명: 1,2,3,6-TETRAHYDROPYRIDINE
분자식: C5H9N
분자량: 83.13

이름 및 동의어

1,2,3,6-Tetrahydropyridine694-05-3Pyridine, 1,2,3,6-tetrahydro-3-piperideinedelta3-PiperidineDelta(3)-piperideine.DELTA.3-PiperidineUNII-26RLS9D25526RLS9D255EINECS 211-766-2NSC 65443NSC-65443

이름 더 보기

1,2,3,6-테트라하이드로피리딘3,6-Dihydro-2H-pyridine1,2,5,6 TETRAHYDROPYRIDINE1,2,3,6-Tetrahydropyridine,98%1,2,3,6-Tetrahydropyridine 97%1,2,3,6-TETRAHYDROPYRIDINE ISO 9001：2015 REACH

UN2410.delta.(sup 3)-PiperidineDTXSID0075289CHEBI:47860Pyridine, 1,2,5,6-tetrahydro-UN 2410delta3PiperidineRefChem:71367

데이터베이스 식별자

CAS: 694-05-3
PubChem CID: 12750
DTXSID: DTXSID0075289
ChEBI: CHEBI:47860
UNII: 26RLS9D255
EC Number: 211-766-2
Nikkaji: J66.610F

물성

구조 계산 물성

XLogP: 0.5
극성 표면적: 12 Å²
수소 결합 공여자 수: 1
수소 결합 수용자 수: 1
회전 가능 결합 수: 0
무거운 원자 수: 6
형식 전하: 0
복잡도: 57

실험 및 물리화학적 성질

Chemical Classes · 2건

Nitrogen Compounds -> Pyridines

Flammable agents - 2nd degree

SpringerMaterials Properties15N nuclear magnetic resonance spectrum

Density0.911 @25 °C

Flash Point43 °C

Boiling Point108 °C @760 [mm Hg]

Melting Point-48 °C

물리화학적 성질

녹는점: 48 °C · −48 °C(lit.)
끓는 점: 108 °C · 108 °C(lit.)
밀도: 0.911 g/mL · 0.911 g/mL at 25 °C(lit.)
굴절률: 20 · n20/D 1.48(lit.)
인화점: 61 °F · 61 °F
용해도: 클로로포름(약간 용해됨), 메탄올(약간 용해됨)
물리적 상태: 가루
산도 계수 (pKa): 10.22 · 10.22±0.10(Predicted)
색상: 흰색~연한 노란색 크림
안정성: 감광성
InChI: 1S/C5H9N/c1-2-4-6-5-3-1/h1-2,6H,3-5H2
InChIKey: FTAHXMZRJCZXDL-UHFFFAOYSA-N
SMILES: C1CC=CCN1
EPA: 1 · Pyridine, 1,2,3,6-tetrahydro- (694-05-3)

화학적 성질

Clear colorless to pale yellow liquid

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H225 (97.6%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 42 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory InformationThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelFlammable Liquid

Fire Hazards · 2건

Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

· HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Health Hazards · 2건

Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

· May cause toxic effects if inhaled or absorbed through skin.

Hazards SummaryMay cause irritation or burns to skin and eyes; [CAMEO] An irritant; May be harmful if ingested, absorbed through skin, or inhaled; [MSDSonline] See Pyridine.

DOT ID and Guide2410 129

안전 및 보호

Fire FightingExcerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

Accidental Release Measures · 2건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2건

Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).

Nonfire Spill ResponseExcerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

Isolation and Evacuation · 2건

Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

Immediate precautionary measure

독성 정보

Adverse EffectsDermatotoxin - Skin burns.

안전 데이터

wgk: 3
ridadr: UN 2410
HS 번호: 29333999
risk_code: 11-36/37/38
hazard_code: F,Xi
safety_code: 16-26-36/37/39
포장분류: II
위험 등급: 3
위험 참고 사항: Irritant/Highly Flammable
Hazard Classifications: Eye Irrit. 2Flam. Liq. 2Skin Irrit. 2STOT SE 3
스토리지 클래스: 3 - Flammable liquids

화학 및 산업

용도 및 제조

UsesUsed to make other chemicals; [CAMEO]

응용 분야

용도Organic intermediate.

일반 설명A colorless liquid. Density 0.913 g / cm3 and insoluble in water. Hence floats on water. Flash point near 110°F. Vapors heavier than air. Used to make other chemicals.