글리세롤 1-올레이트
Glyceryl Monooleate
데이터를 보충하는 중입니다. 잠시 후 페이지를 새로 고치면 최신 내용을 볼 수 있습니다
기본 정보
- CAS
111-03-5- 표준 SMILES
CCCCCCCC/C=C\CCCCCCCC(=O)OCC(O)CO- InChIKey
RZRNAYUHWVFMIP-KTKRTIGZSA-N- 분자식
- C21H40O4
- 평균 분자량
- 356.5 g/mol
- 단동위원소 질량
- 356.29265975
개요
1-oleoylglycerol is a 1-monoglyceride where the acyl group is oleoyl. It has a role as a plant metabolite. It is a 1-acylglycerol 18:1 and a monooleoylglycerol. It is functionally related to an oleic acid.
이름 및 식별자
- 우선 이름
- Glyceryl Monooleate
- IUPAC
- 2,3-dihydroxypropyl (Z)-octadec-9-enoate
- 현지명
- 글리세롤 1-올레이트
- 영어명
- Glyceryl Monooleate
- 분자식
- C21H40O4
- 분자량
- 356.54
이름 및 동의어
MonooleinGlyceryl monooleatealpha-Monoolein25496-72-4Nikkol MGOMonoglyceryl oleateOleic monoglycerideOleoylglycerolOlicineGlycerine monooleateGLYCEROL MONOOLEATESupeol
이름 더 보기
글리세롤1-올레이트글리세롤1-올레이트글리세릴올리에이트Glyceryl oleateGMO9-Octadecenoic acid (Z)-, 2,3-dihydroxypropyl ester1-Monooleoylglycerol1-OLEOYL-RAC-GLYCEROL1-OleoylglycerolAblunol GMOGlycerol oleate
1-Mono(cis-9-octacenoyl)glycerol2,3-dihydroxypropyl (Z)-octadec-9-enoateSinnoester ogcOleylmonoglycerideExcel O 95FDimodan LSQKEmalsy MOEmalsy OL
데이터베이스 식별자
- CAS
111-03-5、25496-72-4- PubChem CID
- 5283468
- DTXSID
DTXSID3042003- ChEMBL
CHEMBL2075039、CHEMBL428593- ChEBI
CHEBI:75342- UNII
- D3AEF6S35P
- EC Number
- 203-827-7、247-038-6
- Nikkaji
- J5.104G
물성
구조 계산 물성보충 중
- XLogP
- 6.5
- 극성 표면적
- 66.8 Ų
- 수소 결합 공여자 수
- 2
- 수소 결합 수용자 수
- 4
- 회전 가능 결합 수
- 19
- 무거운 원자 수
- 25
- 형식 전하
- 0
- 복잡도
- 315
실험 및 물리화학적 성질
Chemical ClassesOther Uses -> Emulsifiers/Surfactants
LipidsLipids -> Glycerolipids [GL] -> Monoradylglycerols [GL01] -> Monoacylglycerols [GL0101]
Fragrances
Fragrance Ingredient (9-Octadecenoic acid (Z)-, monoester with 1,2,3-propanetriol) -> IFRA transparency List
Fragrance Ingredient (Glyceryl monooleate) -> IFRA transparency List
SurfactantsSurfactant
OdorSWEET
TasteFATTY TASTE
Food AdditivesANTICAKING AGENT OR FREE-FLOW AGENT, DRYING AGENT, EMULSIFIER OR EMULSIFIER SALT, FLAVORING AGENT OR ADJUVANT, HUMECTANT -> FDA Substance added to food
Density
0.9420 @ 20 °C/4 °C
0.925-0.935
Color/Form
PLATES FROM ETHANOL
YELLOW OIL OR SOFT SOLID
Solubility
INSOL IN WATER; SOL IN ETHANOL, ETHER, CHLOROFORM
insoluble in water; soluble in hot organic solvents
soluble in hot alcohol (in ethanol)
Boiling Point
238-240 °C AT 3 MM HG
250 °C (8 mmHg)
Melting Point
25 °C (UNSTABLE)
MELTING POINT: 32 °C (UNSTABLE) /PRIMARY BETA FORM/; 35.5 °C (STABLE) /BETA FORM/
물리화학적 성질
- 녹는점
- 35 · 35-37 °C
- 끓는 점
- 409.35 °C · 409.35°C (rough estimate)
- 밀도
- 0.9407 g/cm3 · 0.9407 g/cm3 (35 ºC)
- 굴절률
- 1.46384 · 1.46384 (589.3 nm 35℃)
- FEMA
- 2526 · 2526 | GLYCERYL MONOOLEATE
- 인화점
- 180 °C · 180 °C
- 저장 조건
- 2 · 2-8°C
- 용해도
- 50 mg/mL, · 클로로포름: 50mg/mL, 투명, 무색
- 산도 계수 (pKa)
- 13.16 · 13.16±0.20(Predicted)
- 물리적 상태
- 고체
- 색상
- 흰색에서 황백색까지
- 냄새
- 순한 지방 왁스 같은
- 냄새 유형
- 온화한
- 생물학적 소스
- synthetic (organic)
- JECFA Number
- 919 · 919
- BRN
- 1728976 · 1728976
- 안정성
- 흡습성
- 화장품 원료 기능
- 향수계면활성제 - 유화제피부 컨디셔닝 - 보습제
- InChI
- 1S/C21H40O4/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-21(24)25-19-20(23)18-22/h9-10,20,22-23H,2-8,11-19H2,1H3/b10-9-
- InChIKey
- RZRNAYUHWVFMIP-KTKRTIGZSA-N
- SMILES
- O=C(CCCCCCC/C=C\CCCCCCCC)OCC(O)CO
- LogP
- 6.71 · 6.71
- EPA
- Glycerol monooleate (111-03-5)
화학적 성질
White Waxy Solid
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
This chemical does not meet GHS hazard criteria for 96.9% (492 of 508) of all reports.
Not Classified
Aggregated GHS information provided per 508 reports by companies from 5 notifications to the ECHA C&L Inventory.
This chemical does not meet GHS hazard criteria for 100% (260 of 260) of all reports.
Not Classified
Aggregated GHS information provided per 260 reports by companies from 1 notifications to the ECHA C&L Inventory.
유해성 정보
Regulatory Information
Chemical: 9-Octadecenoic acid, monoester with 1,2,3-propanetriol, (Z)-
9-Octadecenoic acid (9Z)-, monoester with 1,2,3-propanetriol is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 9-Octadecenoic acid (9Z)-, monoester with 1,2,3-propanetriol are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
1-Glyceryl monooleate: Does not have an individual approval but may be used under an appropriate group standard
Glyceryl monooleate: Does not have an individual approval but may be used under an appropriate group standard
Other Safety InformationIMAP assessments - 9-Octadecenoic acid, monoester with 1,2,3-propanetriol, (Z)-: Human health tier I assessment
Hazards SummaryMay cause mild irritation; [MSDSonline]
FDA Requirements
SYNTHETIC FLAVOR INGREDIENTS- GLYCERYL MONOOLEATE: REGULATION 172.515.
REGULATION FDA 121.1164; LIMITATIONS: SYNTHETIC FLAVOR.
EPA Safer Chemical
Chemical: Glyceryl monooleate
Chemical: Glyceryl monooleate [NF]
Hazard Classes and Categories
Not Classified
Not Classified
독성 정보
Human Toxicity Excerpts
TREATMENT OF HUMAN ERYTHROCYTE GHOST MEMBRANES WITH THE FUSOGENIC LIPID GLYCEROL MONOOLEATE INCREASED THE FLUIDITY OF THE MEMBRANE LIPIDS, BUT THE NONFUSOGENIC LIPID GLYCEROL MONOSTEARATE HAD NO EFFECT.
IF ANY OF THESE ESTERS IS SIGNIFICANTLY TOXIC, THE ACID PORTION MUST BE HELD RESPONSIBLE, NOT THE GLYCEROL. /GLYCEROL ESTERS/
규제 정보
FDA Requirements
SYNTHETIC FLAVOR INGREDIENTS- GLYCERYL MONOOLEATE: REGULATION 172.515.
REGULATION FDA 121.1164; LIMITATIONS: SYNTHETIC FLAVOR.
안전 데이터
- wgk
- 1
- tsca
- TSCA listed
- ridadr
- UN 1282 3/PG 2
- HS 번호
- 29161500
- risk_code
- 11-20/21/22
- hazard_code
- F,Xn
- safety_code
- 36/37
- 기존화학 물질
- KE-26468
- F 고인화성물질
- 3
- 스토리지 클래스
- 11 - Combustible Solids
화학 및 산업
용도 및 제조
Uses
Used in foods, pharmaceuticals, cosmetics, rust-preventive oils, vinyl light stabilizers, odorless base paints, textile finishing, and flavoring; Used as emulsifier for liquid and paste waxes, polishes, and cleaners; [Hawley]
Painting (Pigments, Binders, and Biocides) [Category: Paint]
SURFACE-ACTIVE AGENT IN FOODS, PHARMACEUTICALS AND COSMETICS, ODORLESS BASE PAINTS, IN RUST-PREVENTIVE OILS, TEXTILE FINISHING, AND VINYL LIGHT STABILIZERS; FLAVORING INGREDIENT
U.S. Exports
(1972) No Data
(1975) No Data
U.S. Imports
(1972) No Data
(1975) No Data
U.S. Production
2023: 5,000,000 - <10,000,000 lb
(1972) 1.25X10+9 GRAMS
(1975) 1.71X10+9 GRAMS
Consumer UsesSurface modifier
Industry UsesLubricating agent
Methods of Manufacturing
REACTION OF OLEIC ACID WITH GLYCEROL, PRODUCING A MIXTURE (PREDOMINANTLY MONOOLEATE)
SEE MONOGLYCERIDE. PRODUCED SYNTHETICALLY BY ALCOHOLYSIS OF FATS WITH GLYCEROL, YIELDING A MIXTURE OF MONO-, DI-, & TRIGLYCERIDES WHICH IS PREDOMINANTLY MONOGLYCERIDES. /MONOGLYCERIDE/
Formulations/PreparationsGRADES: EDIBLE; TECHNICAL.
Household ProductsInformation on 4 consumer products that contain Glycerol Oleate in the following categories is provided:
Use Classification
EPA Safer Chemical Functional Use Classes -> Surfactants
Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern
EPA Safer Chemical Functional Use Classes -> Surfactants
Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern
Fragrance Ingredients
Fragrance Ingredients
General Manufacturing Information
Wholesale and Retail Trade
9-Octadecenoic acid (9Z)-, 2,3-dihydroxypropyl ester: ACTIVE
9-Octadecenoic acid (9Z)-, monoester with 1,2,3-propanetriol: ACTIVE
FEMA NUMBER 2526
응용 분야
용도Glyceryl Monooleate is a flavoring agent that is prepared by esterification of commercial oleic acid that is derived either from edible sources or from tall oil fatty acids. It contains and glyceryl esters of fatty acids present in commercial oleic acid. The ingredient is also used as an adjuvant and as a solvent and vehicle.
일반 설명1-Oleoyl-rac-glycerol is commonly known as monoolein (MO). It is an amphiphilic molecule that is made up of a glycerol backbone and a hydrocarbon chain.
제조 방법
Glyceryl Monooleate is produced by esterification of Glycerin with Oleic acid in presence of a suitable catalyst.
상·하류 제품 정보
하류 제품
추가 설명
정의ChEBI: A 1-monoglyceride where the acyl group is oleoyl.
관련 반응
32건
화합물 노트
불러오는 중…