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Dichloro(prop-2-enyl)silane → 7-Methyl-4,4,7-trichloro-4,7-disila-1-octene

HRID 37601
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HRID 37601 반응식
[CH:1]([Si:3]([CH3:6])([CH3:5])[Cl:4])=[CH2:2].[CH2:7]([SiH:10]([Cl:12])[Cl:11])[CH:8]=[CH2:9]>C(O)(C)C.[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl>[CH3:5][Si:3]([Cl:4])([CH3:6])[CH2:1][CH2:2][Si:10]([Cl:12])([Cl:11])[CH2:7][CH:8]=[CH2:9]
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참가 물질

5

반응물 2

HCID 77536Dichloro(prop-2-enyl)silaneHCID 519368Chloro(dimethyl)vinylsilane

생성물 1

HCID 572834757-Methyl-4,4,7-trichloro-4,7-disila-1-octene수율 89%

시약·촉매·용매 2

HCID 61859Chloroplatinic acid촉매HCID 3776Isopropanol용매

실험 절차

Using the same apparatus and procedure described in EXAMPLE 1, 25.3 g (0.21 mol) of vinyldimethylchlorosilane and 50 μl of 1% chloroplatinic acid in isopropanol were added to the flask. Through the dropping funnel was added dropwise 10 g (0.07 mol) of allyldichlorosilane for 30 rain at 80° C. and the solution was further reacted for 2 hrs to complete the reaction. Vacuum distillation (48°-52° C./0.5 torr) of the product mixture gave 16.2 g (89%) of 7-methyl-4,4,7-trichloro-4,7-disila-1-octene.

후처리

  1. additionwere added to the flask
  2. customthe solution was further reacted for 2 hrs
  3. customthe reaction
  4. distillationVacuum distillation (48°-52° C./0.5 torr) of the product mixture

출처 및 근거

ORD 기록
ord-6831f982592d4a65a5d5585f07882c34
출처 데이터셋
uspto-grants-1995_05
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US05420323

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