2,4-Diaminobenzenesulfonic acid (HCID 66623)

이름 및 식별자

우선 이름: 2,4-Diaminobenzenesulfonic acid
IUPAC: 2,4-diaminobenzenesulfonic acid
현지명: 2,4-디아미노벤젠 설폰산
영어명: 2,4-Diaminobenzenesulfonic acid
분자식: C6H8N2O3S
분자량: 188.2

이름 및 동의어

2,4-Diaminobenzenesulfonic acid88-63-11,3-Phenylenediamine-4-sulfonic acido-Aminosulfanilic acidBenzenesulfonic acid, 2,4-diamino-1,3-Diaminobenzene-4-sulfonic acidm-Phenylenediamine-4-sulfonic acid1,3-Diaminobenzene-6-sulfonic acidDTXSID3044465NSC-7835863X637R5QDTXCID1024465

이름 더 보기

2,4-디아미노벤젠설폰산1,3-페닐렌다이아민-4-술폰산2,4-디아미노벤젠설폰산1,3-다이아미노벤젠-4-술폰산1,3-다이아미노벤젠-6-술폰산1,3-다이아미노벤젠술폰산2,4-다이아미노젠젠술폰산4-술포-1,3-다이아미노벤젠m-페닐렌다이아민-4-술폰산MPDSA3-AMINO-4-SULFOANILINE2,4-DIAMINO-1-SULFOBENZENE4-Sulfo-1,3-diaminobenzenem-Diaminobenzenesulfonicacid2,4-diamino-benzenesulfonicaci1,3-Phenylendiamin-4-sulfonsure

RefChem:822751,3-phenylenediamine-4-sulfo acid201-846-52,4-diaminobenzene-1-sulfonic acid2,4-Diaminobenzenesulphonic acidm-Phenylenediaminesulfonic acid1,3-Diaminobenzenesulfonic acidMFCD00035772

데이터베이스 식별자

CAS: 88-63-1
PubChem CID: 66623
DTXSID: DTXSID3044465
ChEMBL: CHEMBL3184102
UNII: 863X637R5Q
EC Number: 201-846-5
Nikkaji: J54.504J

물성

구조 계산 물성

XLogP: -1
극성 표면적: 115 Å²
수소 결합 공여자 수: 3
수소 결합 수용자 수: 5
회전 가능 결합 수: 1
무거운 원자 수: 12
형식 전하: 0
복잡도: 246

실험 및 물리화학적 성질

Collision Cross Section137.9 Å² [M-H]- [CCS Type: DT; Buffer gas: N2; Ionization: ESI-; Dataset: TOXCAST; Source Identifier: DTXSID3044465]

물리화학적 성질

녹는점: 260 · 260-266 °C (dec.)
끓는 점: 500 °C · 500°C (estimate)
밀도: 1.366 · 1.366 (estimate)
증기압: 0 Pa · 0Pa at 25℃
굴절률: 1.649 · 1.6490 (estimate)
저장 조건: -20 °C · -20°C Freezer, Under inert atmosphere
용해도: DMSO(약간 용해됨, 가열), 메탄올(약간 용해됨)
물리적 상태: 고체
산도 계수 (pKa): 2.99 · 2.99±0.10(Predicted)
색상: 흰색에서 연한 노란색
수용성: 1000 g/L · 1000g/L at 25℃
BRN: 2694057 · 2694057
InChI: 1S/C6H8N2O3S/c7-4-1-2-6(5(8)3-4)12(9,10)11/h1-3H,7-8H2,(H,9,10,11)
InChIKey: JVMSQRAXNZPDHF-UHFFFAOYSA-N
SMILES: Nc1ccc(c(N)c1)S(O)(=O)=O
LogP: -4.65 · -4.65
EPA: 2 · Benzenesulfonic acid, 2,4-diamino- (88-63-1)

화학적 성질

brown crystalline powder

안전 및 규제

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 11.1% (10 of 90) of reports.

Warning

H315 (83.3%): Causes skin irritation [Warning Skin corrosion/irritation]；H317 (81.1%): May cause an allergic skin reaction [Warning Sensitization, Skin]；H319 (83.3%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]

P261, P264, P264+P265, P272, P280, P302+P352, P305+P351+P338, P321, P332+P317, P333+P317, P337+P317, P362+P364, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 90 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Reported as not meeting GHS hazard criteria per 10 of 90 reports by companies.；There are 5 notifications provided by 80 of 90 reports by companies with hazard statement code(s).；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory Information · 2건

Chemical: Benzenesulfonic acid, 2,4-diamino-

Status: Active Update: 23-04-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/17689；Status: Active Update: 11-03-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/27862

Hazard Classes and CategoriesSkin Irrit. 2 (83.3%)；Skin Sens. 1 (81.1%)；Eye Irrit. 2 (83.3%)

규제 정보

Regulatory Information · 2건

Chemical: Benzenesulfonic acid, 2,4-diamino-

Status: Active Update: 23-04-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/17689；Status: Active Update: 11-03-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/27862

안전 데이터

wgk: 2
tsca: TSCA listed
rtecs: DB5900000
ridadr: 1759
HS 번호: 29309090
risk_code: 36/38-43-36/37/38
hazard_code: Xi
safety_code: 26-36/39-37/39-36
포장분류: III
위험 등급: 8
기존화학 물질: KE-28347
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2Skin Sens. 1
스토리지 클래스: 11 - Combustible Solids

화학 및 산업

용도 및 제조

General Manufacturing InformationBenzenesulfonic acid, 2,4-diamino-: ACTIVE

응용 분야

용도2,4-Diaminobenzenesulfonic acid was used in preparation of series of sulfonated homo- and random co-polyimides.

일반 설명2,4-Diaminobenzenesulfonic acid is an sulfonated aromatic amine and its aerobic biodegradation was reported.

제조 방법 · 1건

생산 방법2,4-Diaminobenzenesulfonic acid is obtained by sulfonating a solution of m-phenylenediamine in 100% sulfuric acid with oleum at 155 ℃, adding water to the sulfonation mixture, desulfonating the resulting disulfonic acids at 140 ℃, and isolating the free acid at 10 ℃; yield 93%. Another process starts from 1-chloro-2,4-dinitrobenzene, which, as an alcoholic solution, is reacted with sodium sulfite solution to form 2,4-dinitrobenzenesulfonic acid, from which the end product is obtained by reduction with iron according to BE′CHAMP.

상·하류 제품 정보

상류 원료

하류 제품

Reactive Brilliant Blue M-BR 모단트브라운49 REACTIVE BLUE 4 리액티브다크블루M-2ge C.I. REACTIVE 황색 2 리액티브네이비블루커 disodium 2,5-dichloro-4-[4-[[5-[(4,6-dichloro-1,3,5-triazin-2-yl)amino]-2-sulphonatophenyl]azo]-4,5-dihydro-3-methyl-5-oxo-1H-pyrazol-1-yl]benzenesulphonate disodium 4-[[2,4-diamino-5-[(3-sulphonatophenyl)azo]phenyl]azo]-2-[[2,6-dihydroxy-3-[(4-nitrophenyl)azo]phenyl]azo]benzenesulphonate 몰단도브라운33 리액티브옐로우179 Neutral Brilliant Yellow S-5GL 산성황색127

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

苏州启航生物科技有限公司18151111370 · [email protected]

武汉欣扬瑞和化学科技有限公司153-07155313 15307155313 · [email protected]

연결된 노트

불러오는 중…

2,4-디아미노벤젠 설폰산

기본 정보