Bis(2-ethylhexyl)amine (HCID 7791)

개요

2,2'-diethylhexylamine is a clear colorless liquid with a slight ammonia-like odor. (NTP, 1992)

이름 및 식별자

우선 이름: Bis(2-ethylhexyl)amine
IUPAC: 2-ethyl-N-(2-ethylhexyl)hexan-1-amine
현지명: 디-2-에틸헥실아민
영어명: Bis(2-ethylhexyl)amine
분자식: C16H35N
분자량: 241.46

이름 및 동의어

Bis(2-ethylhexyl)amine106-20-71-Hexanamine, 2-ethyl-N-(2-ethylhexyl)-RefChem:1079934Di(2-ethylhexyl)amineBis-2-ethylhexylamine2-ethyl-N-(2-ethylhexyl)hexan-1-amine2,2'-DiethyldihexylamineDiethylhexylamineDihexylamine, 2,2'-diethyl-2,2'-DIETHYLHEXYLAMINENSC 5329

이름 더 보기

디-2-에틸헥실아민비스(2-에틸헥실)아민다이에틸헥실아민2,2'-다이에틸다이헥실아민2,2'-디에틸헥실아민2-에틸-N-(2-에틸헥실)-1-헥산아민2-에틸-N-(2-에틸헥실)헥산-1-아민N,N-비스(2-에틸헥실)아민다이-(2-에틸헥실)-아민다이(2-에틸헥실)아민다이-2-에틸헥실아민다이헥실아민, 2,2'-다이에틸-DIISOOCTYLAMINED2HDI2 EHAis2-ethylhexyl4-DifluorobenzoateTwo isooctyl amineTwo-ethylhexyl aMineBis(2-ethylhexyl)amiBis-2-ethylhexylamin

2-Ethyl-N-(2-ethylhexyl)-1-hexanamineDTXSID7025053MFCD0000948927214-52-49U5Q5UV6DBNSC-5329Di-(2-ethylhexyl)amine1-Hexylamine, 2-ethyl-N-(2-ethylhexyl)-

데이터베이스 식별자

CAS: 106-20-7、27214-52-4
PubChem CID: 7791
DTXSID: DTXSID7025053
ChEMBL: CHEMBL1330355
ChEBI: CHEBI:193588
UNII: 9U5Q5UV6DB
EC Number: 203-372-4、248-331-1
Nikkaji: J27.961G

물성

구조 계산 물성

XLogP: 6.1
극성 표면적: 12 Å²
수소 결합 공여자 수: 1
수소 결합 수용자 수: 1
회전 가능 결합 수: 12
무거운 원자 수: 17
형식 전하: 0
복잡도: 128

실험 및 물리화학적 성질

Chemical ClassesNitrogen Compounds -> Amines, Aliphatic

Cosmetics · 2건

Personal care product

Antistatic; Hair conditioning

SpringerMaterials PropertiesOptical coefficient

Density0.8062 at 68 °F (NTP, 1992) - Less dense than water; will float

Solubilityless than 1 mg/mL at 70 °F (NTP, 1992)

Flash Point · 2건

270 °F (NTP, 1992)

270 °F

물리화학적 성질

녹는점: -60 °C · -60 °C
끓는 점: 123 °C5 · 123 °C5 mm Hg(lit.)
밀도: 0.805 g/mL · 0.805 g/mL at 25 °C(lit.)
증기압: 0.0023 hPa · 0.0023 hPa (20 °C)
굴절률: 20 · n20/D 1.443(lit.)
인화점: 230 °F · >230 °F
저장 조건: 30 °C · Store below +30°C.
용해도: 0.014 g/L · 0.014g/L
산도 계수 (pKa): 40 · 40(at 25℃)
물리적 상태: 액체
색상: 무색투명~미황색
Specific Gravity: 0.804 · 0.804 (20/4℃)
수소이온지수(pH): 7 · >7 (H2O, 20℃)
폭발한계: 0.6 · 0.6-3.7%(V)
수용성: 0.2 g/L · <0.2g/L(20℃)
BRN: 1748342 · 1748342
안정성: 안정적인. 타기 쉬운. 산화제와 호환되지 않습니다.
화장품 원료 기능: 대전방지제
InChI: 1S/C16H35N/c1-5-9-11-15(7-3)13-17-14-16(8-4)12-10-6-2/h15-17H,5-14H2,1-4H3
InChIKey: SAIKULLUBZKPDA-UHFFFAOYSA-N
SMILES: CCCCC(CC)CNCC(CC)CCCC
LogP: 7.3 at · 7.3 at 25℃
NIST: 1 · 1-Hexanamine, 2-ethyl-N-(2-ethylhexyl)-(106-20-7)
EPA: Di(2-ethylhexyl)amine (106-20-7)

화학적 성질

colourless liquid

안전 및 규제

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 0.1% (1 of 669) of reports.

Danger

H302+H312 (65.9%): Harmful if swallowed or in contact with skin [Warning Acute toxicity, oral; acute toxicity, dermal]

P260, P261, P262, P264, P264+P265, P270, P271, P273, P280, P284, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P320, P321, P330, P361+P364, P362+P364, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 669 reports by companies from 17 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Not Classified

유해성 정보

Regulatory Information · 4건

Chemical: 1-Hexanamine, 2-ethyl-N-(2-ethylhexyl)-

1-Hexanamine, 2-ethyl-N-(2-ethylhexyl)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1-Hexanamine, 2-ethyl-N-(2-ethylhexyl)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 13-04-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/5450

Bis(2-ethylhexyl) amine: Does not have an individual approval but may be used under an appropriate group standard

DOT LabelCorrosive

Fire HazardsThis chemical is combustible. (NTP, 1992)

Health HazardsSYMPTOMS: Symptoms of exposure to this compound may include irritation to the skin and eyes.

Hazards SummaryA skin and eye irritant; A lachrymator; [CAMEO] Toxic by inhalation; Harmful if skin contact or ingested; Causes burns; May cause pneumonitis and pulmonary edema after inhalation of high concentrations; [MSDSonline]

Reactive GroupAmines, Phosphines, and Pyridines

안전 및 보호

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide, or Halon extinguisher. (NTP, 1992)

First Aid · 1건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1건

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:

Personal Protective Equipment (PPE) · 1건

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

독성 정보

Adverse EffectsDermatotoxin - Skin burns.

Toxicity DataLC50 (rat) = 920 mg/m3/4H; [MSDSonline]

안전 데이터

wgk: 2
tsca: TSCA listed
rtecs: IH6825000
ridadr: UN 2735 8/PG 2
독성: LD50 orally in Rabbit: 1008 mg/kg LD50 dermal Rabbit 956 mg/kg
HS 번호: 29211980
risk_code: 21/22-34
hazard_code: C,Xi
safety_code: 26-36/37/39-45-36
포장분류: III
위험 등급: 8
기존화학 물질: KE-05-0210
위험 참고 사항: Irritant/Corrosive
자연 발화 온도: 230 °C
Hazard Classifications: Acute Tox. 3 DermalAcute Tox. 3 InhalationAcute Tox. 4 OralAquatic Chronic 1Eye Dam. 1Skin Corr. 1B
스토리지 클래스: 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials
함량 및 규제정보: 물질구분: 유독물질; 혼합물(제품)함량정보: 비스(2-에틸헥실)아민 및 이를 25% 이상 함유한 혼합물
유해화학물질 필터링: 97-1-120

화학 및 산업

용도 및 제조

U.S. Production2023: 100,000 - <250,000 lb

Industry UsesCorrosion inhibitor

Use ClassificationCosmetics -> Antistatic; Hair conditioning

General Manufacturing Information · 2건

Petroleum Lubricating Oil and Grease Manufacturing

1-Hexanamine, 2-ethyl-N-(2-ethylhexyl)-: ACTIVE

응용 분야

용도Bis(2-ethylhexyl)amine (BEA) was used in the synthesis of stable nanosized CdS particles coated by an oriented monolayer of chemically bonded BEA molecules

일반 설명Clear colorless liquid with a slight ammonia-like odor.