Bis(2-ethylhexyl)amine → 4-chloro-N,N-bis(2-ethylhexyl)butanamide

반응식

[CH3:1][CH2:2][CH2:3][CH2:4][CH:5]([CH2:8][NH:9][CH2:10][CH:11]([CH2:14][CH2:15][CH2:16][CH3:17])[CH2:12][CH3:13])[CH2:6][CH3:7].[Cl:18][CH2:19][CH2:20][CH2:21][C:22](Cl)=[O:23]>>[Cl:18][CH2:19][CH2:20][CH2:21][C:22]([N:9]([CH2:8][CH:5]([CH2:6][CH3:7])[CH2:4][CH2:3][CH2:2][CH3:1])[CH2:10][CH:11]([CH2:12][CH3:13])[CH2:14][CH2:15][CH2:16][CH3:17])=[O:23]

참가 물질

반응물 2

HCID 7791Bis(2-ethylhexyl)amine

HCID 783704-Chlorobutyryl chloride

생성물 1

HCID 1180597934-chloro-N,N-bis(2-ethylhexyl)butanamide

실험 절차

Step A is conducted starting from 2,2′-diethylhexylamine and 4-chlorobutanoyl chloride and leads to 4-chloro-N,N-bis(2-ethylhexyl)butanamide (Yield: quantitative) for which the 1H and 13C NMR characterisations give:

출처 및 근거

ORD 기록: ord-a393b274c75e4186b0442b2b1cc0f811
출처 데이터셋: uspto-grants-2016_09
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US09441285B2

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