Bromomethylcyclopropane (HCID 81503)

이름 및 식별자

우선 이름: Bromomethylcyclopropane
IUPAC: bromomethylcyclopropane
영어명: (Bromomethyl)cyclopropane
분자식: C4H7Br
분자량: 135

이름 및 동의어

(Bromomethyl)cyclopropane7051-34-5BromomethylcyclopropaneCyclopropane, (bromomethyl)-1-(bromomethyl)cyclopropaneCyclopropanemethyl bromideD8ZPP7X54BEINECS 230-331-8DTXSID40220785(BROMO)(CYCLOPROPYL)METHANERefChem:121604DTXCID70143276

이름 더 보기

Cyclopropylcarbinyl bromideCPMBr(Bromomethyl)cyclopr(Xiu Jiaji)cyclopropaneBroMoMethyl)cyclopropanCyclopropylmethylbromidRoflumilast impurity 18CYCLOPROPYLMETYL BROMIDE

230-331-8AEILLAXRDHDKDY-UHFFFAOYSA-NCyclopropylmethyl bromideMFCD00001306bromocyclopropylmethaneCyclopropyl bromo methanebromomethyl cyclopropanecyclopropylmethylbromide

데이터베이스 식별자

CAS: 7051-34-5
PubChem CID: 81503
DTXSID: DTXSID40220785
UNII: D8ZPP7X54B
EC Number: 230-331-8
Nikkaji: J23.250E

물성

구조 계산 물성

XLogP: 1.7
극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 0
회전 가능 결합 수: 1
무거운 원자 수: 5
형식 전하: 0
복잡도: 30

물리화학적 성질

녹는점: 87 · 87-90 °C
끓는 점: 105 · 105-107 °C(lit.)
밀도: 1.392 g/mL · 1.392 g/mL at 25 °C(lit.)
굴절률: 20 · n20/D 1.457(lit.)
인화점: 107 °F · 107 °F
저장 조건: 2 · Inert atmosphere,2-8°C
용해도: 클로로포름(약간 용해됨), 메탄올(약간 용해됨)
물리적 상태: 액체
Specific Gravity: 1.392 · 1.392
색상: 무색, 투명 또는 약간 착색됨
수용성: 물과 섞이지 않습니다.
BRN: 605296 · 605296
안정성: 안정적인. 가연성. 강염기, 강산화제와 호환되지 않습니다.
InChI: 1S/C4H7Br/c5-3-4-1-2-4/h4H,1-3H2
InChIKey: AEILLAXRDHDKDY-UHFFFAOYSA-N
SMILES: BrCC1CC1
NIST: Cyclopropane, (bromomethyl)-(7051-34-5)

화학적 성질

Colorless to yellow liquid

안전 및 규제

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 0.5% (1 of 182) of reports.

Danger

H225 (57.1%): Highly Flammable liquid and vapor [Danger Flammable liquids]；H226 (42.3%): Flammable liquid and vapor [Warning Flammable liquids]；H302 (70.9%): Harmful if swallowed [Warning Acute toxicity, oral]；H315 (69.8%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (69.2%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (68.7%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 182 reports by companies from 16 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Reported as not meeting GHS hazard criteria per 1 of 182 reports by companies.；There are 15 notifications provided by 181 of 182 reports by companies with hazard statement code(s).；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory Information · 3건

Chemical: Cyclopropane, (bromomethyl)-

Status: Active Update: 06-03-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/21443

Bromomethyl-cyclopropane: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesFlam. Liq. 2 (57.1%)；Flam. Liq. 3 (42.3%)；Acute Tox. 4 (70.9%)；Skin Irrit. 2 (69.8%)；Eye Irrit. 2A (69.2%)；STOT SE 3 (68.7%)

규제 정보

Regulatory Information · 3건

Chemical: Cyclopropane, (bromomethyl)-

Status: Active Update: 06-03-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/21443

Bromomethyl-cyclopropane: Does not have an individual approval but may be used under an appropriate group standard

안전 데이터

wgk: 3
ridadr: UN 1993 3/PG 3
HS 번호: 29035990
risk_code: 10-36/37/38-22
hazard_code: Xi,F,Xn
safety_code: 23-24/25-37/39-26-16-36/37/39
포장분류: III
위험 등급: 3
위험 참고 사항: Irritant
Hazard Classifications: Acute Tox. 4 OralFlam. Liq. 3
스토리지 클래스: 3 - Flammable liquids

화학 및 산업

응용 분야

용도(Bromomethyl)cyclopropane was used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.

일반 설명The coupling reaction of (bromomethyl)cyclopropane with phenylmagnesium bromide was studied.

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]

衢州润东化工有限公司0570-8789886 18892685668 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

T&W GROUP021-61551611 13296011611 · [email protected]

韶远科技（上海）有限公司021-50795510 4000665055 · [email protected]

연결된 노트

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Bromomethylcyclopropane

기본 정보