Aluminum(III) Chloride → 4-Iodo-3-nitro-benzophenone

HRID 1017791

반응식

HRID 1017791 반응식
[I:1][C:2]1[CH:10]=[CH:9][C:5]([C:6]([OH:8])=O)=[CH:4][C:3]=1[N+:11]([O-:13])=[O:12].[Cl-].[Cl-].[Cl-].[Al+3]>C1C=CC=CC=1>[I:1][C:2]1[CH:10]=[CH:9][C:5]([C:6]([C:2]2[CH:10]=[CH:9][CH:5]=[CH:4][CH:3]=2)=[O:8])=[CH:4][C:3]=1[N+:11]([O-:13])=[O:12]

참가 물질

4

반응물 2

HCID 6451240Aluminum(III) ChlorideHCID 112085984-Iodo-3-nitrobenzoic acid

생성물 1

HCID 111873024-Iodo-3-nitro-benzophenone

시약·촉매·용매 1

HCID 241Benzene용매

실험 절차

5.3 g (17 mmol) of 4-iodo-3-nitrobenzoic acid and 8.0 g (60 mmol) of aluminium trichloride are added successively to 70 ml of benzene while cooling with an ice bath. Then the mixture is stirred for 2 hours at ambient temperature, then poured into ice water, extracted with methylene chloride, dried with sodium sulphate and concentrated in vacuo.

후처리

  1. temperaturewhile cooling with an ice bath
  2. extractionextracted with methylene chloride
  3. dry with materialdried with sodium sulphate
  4. concentrationconcentrated in vacuo

출처 및 근거

ORD 기록
ord-2af6b35e3597405292621887034b7779
출처 데이터셋
uspto-grants-2002_11
특허 번호
US06479524B1

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