Carbon Disulfide → HCID 178446353, 화합물

HRID 1032865

반응식

HRID 1032865 반응식
[OH-].[Na+].[CH2:3]([NH:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[CH2:4][CH2:5][CH2:6][CH3:7].[C:14](=[S:16])=[S:15].[W:17](Cl)(Cl)(Cl)(Cl)(Cl)Cl>CO>[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[W+6:17]

참가 물질

6

반응물 4

HCID 6348Carbon DisulfideHCID 14798Sodium HydroxideHCID 16316DipentylamineHCID 83301Tungsten hexachloride

생성물 1

HCID 178446353HCID 178446353, 화합물

시약·촉매·용매 1

HCID 887Methanol용매2회

실험 절차

0.576 kg of granulated caustic soda is added to 8 liters of anhydrous methanol and the mixture is stirred until all solid material has dissolved. 2.26 kg of diamylamine are added to the solution and 0.88 liter of carbon disulfide is introduced over a period of 2 hours. The mixture is stirred for a further 3 hours at 25° C. and a solution of 0.952 kg of tungsten hexachloride in 2.4 liters of anhydrous methanol is then added over a period of one hour and the mixture is stirred for an additional 3 hours.

후처리

  1. dissolutionhas dissolved
  2. additionis introduced over a period of 2 hours
  3. stirringThe mixture is stirred for a further 3 hours at 25° C.
  4. stirringthe mixture is stirred for an additional 3 hours

출처 및 근거

ORD 기록
ord-509824005bfb4f039a021a270549f27e
출처 데이터셋
uspto-grants-1994_05
특허 번호
US05308519

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