Dimethyl Carbonate → HCID 68527440, 화합물

반응식

[CH3:1][N:2]1[C:6]2[CH2:7][CH2:8][CH2:9][CH2:10][C:11](=[O:12])[C:5]=2[CH:4]=[N:3]1.[H-].[Na+].[CH3:15][O:16][C:17](=O)[O:18]C>>[CH3:1][N:2]1[C:6]2[CH2:7][CH2:8][CH2:9][CH:10]([C:17]([O:16][CH3:15])=[O:18])[C:11](=[O:12])[C:5]=2[CH:4]=[N:3]1

참가 물질

반응물 3

HCID 12021Dimethyl Carbonate

HCID 24758Sodium hydride

HCID 201465961-methyl-1H,4H,5H,6H,7H,8H-cyclohepta[c]pyrazol-4-one

생성물 1

HCID 68527440HCID 68527440, 화합물

실험 절차

A solution of 1-methyl-5,6,7,8-tetrahydro-1H-cycloheptapyrazol-4-one (0.75 g, 4.6 mmol) in dimethylcarbonate (3 mL) is treated with 60% dispersion of sodium hydride in oil (0.4 g, 10 mmol) as described in Example 1A to yield the title compound: MS (DCI/NH3) m/z 223 (M+H)+.

출처 및 근거

ORD 기록: ord-fb7d282f8a254fd684529612fd7ea7cd
출처 데이터셋: uspto-grants-2013_10
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08546410B2

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