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Dimethyl Sulfoxide → 1-Ethenyl-4-(2-methylpropyl)benzene

HRID 1065535
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HRID 1065535 반응식
[CH2:1]([C:5]1[CH:10]=[CH:9][C:8]([CH:11](O)[CH3:12])=[CH:7][CH:6]=1)[CH:2]([CH3:4])[CH3:3].CS(C)=O>O.[N+](C1C=CC=C([N+]([O-])=O)C=1)([O-])=O>[CH2:1]([C:5]1[CH:6]=[CH:7][C:8]([CH:11]=[CH2:12])=[CH:9][CH:10]=1)[CH:2]([CH3:4])[CH3:3]
참가 물질반응 조건실험 절차후처리출처 및 근거반응 노트

참가 물질

5

반응물 2

HCID 679Dimethyl SulfoxideHCID 1816541-(4-Isobutylphenyl)ethanol

생성물 1

HCID 5761461-Ethenyl-4-(2-methylpropyl)benzene수율 77.9%

시약·촉매·용매 2

HCID 74521,3-Dinitrobenzene촉매HCID 962Water용매

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온도
160 °C

실험 절차

이 페이지에서참가 물질반응 조건실험 절차후처리출처 및 근거반응 노트

To 6 g of α-(4-isobutylphenyl)ethyl alcohol were added 12 g of dimethyl sulfoxide and 0.1 g of m-dinitrobenzene as a polymerization inhibitor. The mixture was stirred at 160° C. for 8 hours. The resultant reaction liquor was cooled, diluted with water and then subjected to extraction with benzene. After the resulting organic layer was dried with magnesium sulfate, the solvent was distilled off. The residue thus obtained was distilled to give 4.2 g of 4-isobutylstyrene having the following physical properties.

후처리

  1. customThe resultant reaction liquor
  2. temperaturewas cooled
  3. extractionsubjected to extraction with benzene
  4. dry with materialAfter the resulting organic layer was dried with magnesium sulfate
  5. distillationthe solvent was distilled off
  6. customThe residue thus obtained
  7. distillationwas distilled

출처 및 근거

ORD 기록
ord-4f7cd24f87a6423989f723a73b4ad459
출처 데이터셋
uspto-grants-1982_05
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04329507

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