Benzyl Chloride → Benzene, [(trichlorosilyl)methyl]-

HRID 1068519

반응식

C(N(CC)CC)C.[CH2:8](Cl)[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.[Cl:16][SiH:17]([Cl:19])[Cl:18]>>[CH2:8]([Si:17]([Cl:19])([Cl:18])[Cl:16])[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1

참가 물질

반응물 3

HCID 7503Benzyl Chloride

HCID 8471Triethylamine

HCID 24811Trichlorosilane

생성물 1

HCID 69863Benzene, [(trichlorosilyl)methyl]-수율 47%

실험 절차

In the same apparatus and procedure as Example 1 above, 0.051 g (0.5 mmol) of triethylamine, 0.63 g (5.0 mmol) of benzyl chloride, and 3.41 g (25.2 mmol) of trichlorosilane were reacted at 150° C. for 18 hrs. The resulting mixture was distilled to give 0.52 g of benzyltrichlorosilane (yield; 47%).

후처리

distillationThe resulting mixture was distilled

출처 및 근거

ORD 기록: ord-387cd971282c408698d108b0b3714455
출처 데이터셋: uspto-grants-2001_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06251057B1

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