Benzyl Chloride → Benzene, [(trichlorosilyl)methyl]-

HRID 1068521

반응식

HRID 1068521 반응식
CN(C)CCN(C)C.[CH2:9](Cl)[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1.[Cl:17][SiH:18]([Cl:20])[Cl:19]>>[CH2:9]([Si:18]([Cl:20])([Cl:19])[Cl:17])[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1

참가 물질

4

반응물 3

HCID 7503Benzyl ChlorideHCID 8037N,N,N',N'-TetramethylethylenediamineHCID 24811Trichlorosilane

생성물 1

HCID 69863Benzene, [(trichlorosilyl)methyl]-수율 52%

실험 절차

In the same apparatus and procedure as Example 1 above, 0.116 g (1.0 mmol) of N,N,N′,N′-tetramethylethylenediamine, 0.63 g (5.0 mmol) of benzyl chloride, and 3.41 g (25.2 mmol) of trichlorosilane were reacted at 200° C. for 7 hrs. The resulting mixture was distilled to give 0.57 g of benzyltrichlorosilane (yield; 52%).

후처리

  1. distillationThe resulting mixture was distilled

출처 및 근거

ORD 기록
ord-816df09f590547248715d676c0189914
출처 데이터셋
uspto-grants-2001_06
특허 번호
US06251057B1

연결된 노트

불러오는 중…