Pyridine → Benzene, [(trichlorosilyl)methyl]-

HRID 1068522

반응식

N1C=CC=CC=1.[CH2:7](Cl)[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1.[Cl:15][SiH:16]([Cl:18])[Cl:17]>>[CH2:7]([Si:16]([Cl:18])([Cl:17])[Cl:15])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1

참가 물질

반응물 3

HCID 1049Pyridine

HCID 7503Benzyl Chloride

HCID 24811Trichlorosilane

생성물 1

HCID 69863Benzene, [(trichlorosilyl)methyl]-수율 11%

실험 절차

In the same apparatus and procedure as Example 1 above, 0.08 g (1.0 mmol) of pyridine, 0.63 g (5.0 mmol) of benzyl chloride, and 3.41 g (25.2 mmol) of trichlorosilane were reacted at 200° C. for 6 hrs. The resulting mixture was distilled to give 0.12 g of benzyltrichlorosilane (yield; 11%).

후처리

distillationThe resulting mixture was distilled

출처 및 근거

ORD 기록: ord-742d3d2df58f4c96b4dbd7fc7f874d68
출처 데이터셋: uspto-grants-2001_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06251057B1

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