Hydrogen Sulfide → Bis dodecyl phenol sulphide

HRID 1076008

반응식

[CH2:1]([C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=1[OH:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[S].[OH-].[Na+].[SH2:23]>>[CH2:10]([C:18]1[C:13]2([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])[S:23][C:14]2([OH:19])[CH:15]=[CH:16][CH:17]=1)[CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH2:1][CH2:13][CH3:14]

참가 물질

반응물 4

HCID 402Hydrogen Sulfide

HCID 14798Sodium Hydroxide2회

HCID 1711442-Dodecylphenol

HCID 5362487Sulfur

생성물 1

HCID 86733380Bis dodecyl phenol sulphide

실험 절차

A mixture of dodecyl phenol (1.0m., 262g.), sulphur (1.0m., 32g.) and caustic soda (8g.) was heated, with stirring, under nitrogen, at 160° C until the evolution of hydrogen sulphide ceased (42 hrs.). The caustic soda was neutralized with 10 ml. of phosphoric acid (SG = 1.75) and the mixture was then filtered. %S of Product = 5.85 (calc. = 5.8).

후처리

temperaturewas heated
custom(42 hrs.)
filtrationof phosphoric acid (SG = 1.75) and the mixture was then filtered

출처 및 근거

ORD 기록: ord-cab618fac034433f919109032ac0567e
출처 데이터셋: uspto-grants-1976_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US03954808

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