Vinyltrichlorosilane → HCID 54184956, 화합물

HRID 1076730

반응식

HRID 1076730 반응식
[C:1]1([CH:7]([SH:9])[CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH:10]([Si:12]([Cl:15])([Cl:14])[Cl:13])=[CH2:11]>N(C(C)(C)C#N)=NC(C)(C)C#N>[Si:12]([CH2:10][CH2:11][S:9][CH:7]([C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)[CH3:8])([Cl:15])([Cl:14])[Cl:13]

참가 물질

4

반응물 2

HCID 6413VinyltrichlorosilaneHCID 1418501-Phenylethanethiol

생성물 1

HCID 54184956HCID 54184956, 화합물

시약·촉매·용매 1

HCID 6547Azobisisobutyronitrile촉매

실험 절차

Into a 500 ml. three-necked flask were charged 108 g. (0.78 mole) 1-phenyl-ethanethiol, 126 g. (0.78 mole) vinyltrichlorosilane and 1.2 g. (0.5 weight percent) azobisisobutyronitrile catalyst. The contents were heated and stirred for 6 hours at 80°-90°C. Fractional distillation of the reaction mixture gave the product fraction, Cl3SiCH2CH2SCH(CH3)C6H5, b.p. 110°/0.53 mm Hg. Vapor phase chromatographic analysis of the distilled product (120 g.) showed it contained a mixture of alpha and beta isomers. Yield of (1-phenylethylthio)ethyltrichlorosilane was 85 percent, based on ViSiCl3 reacted.

후처리

  1. additionthree-necked flask were charged 108 g
  2. temperatureThe contents were heated
  3. distillationFractional distillation of the reaction mixture

출처 및 근거

ORD 기록
ord-614b595473be49a4b4ac777924a35266
출처 데이터셋
uspto-grants-1976_05
특허 번호
US03957844

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