Octanoic Acid → Glyceryl Dibehenate

HRID 1082035

반응식

HRID 1082035 반응식
CCCCCCCCCC(O)=O.CCCCCCCC(O)=O.[CH3:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][C:44]([O:46][CH2:47][CH:48]([OH:51])[CH2:49][OH:50])=[O:45]>>[C:44]([OH:46])(=[O:45])[CH2:43][CH2:42][CH2:41][CH2:40][CH2:39][CH2:38][CH2:37][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH2:24][CH3:23].[OH:46][CH2:47][CH:48]([CH2:49][OH:50])[OH:51]

참가 물질

4

반응물 3

HCID 379Octanoic AcidHCID 2969Decanoic AcidHCID 5362585Glyceryl Monobehenate3회

생성물 1

HCID 22477175Glyceryl Dibehenate

실험 절차

Typically, about 118 kg of a mixture of C10:0 and C8:0 fatty acids (55:45 weight ratio) is preheated to the esterification temperature and adjusted to the requisite pressure. This fatty acid mixture is used to esterify about 16.8 kg of monobehenin at an 18:1 acid to monobehenin mole ratio at esterification temperature 245° C. (The monobehenin is commercially produced by molecular distillation of behenic acid/glycerol reaction products and comprises 98.1% monoglyceride, 0.5% diglyceride, 0.1% free glycerol, and 0.3% diglycerol.) The monobehenin is added incrementally as a liquid over a 60 minute period to the melted fatty acids. The esterification pressure ranges from 700 mmHg to 1520 mmHg. A pressure of 700 mmHg is initially used, but is increased as necessary to prevent the mixture containing the fatty acids from boiling over.

후처리

  1. customat esterification temperature 245° C.

출처 및 근거

ORD 기록
ord-35fe91295af94c65b12b5235cdffd3b6
출처 데이터셋
uspto-grants-1996_12
특허 번호
US05589216

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