Benzotrichloride → N,N'-Bis(4-n-octylcarbamylphenyl)benzamidine
반응식
[NH2:1][C:2]1[CH:18]=[CH:17][C:5]([C:6]([NH:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])=[O:7])=[CH:4][CH:3]=1.Cl[C:20](Cl)(Cl)[C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1>C(Cl)(Cl)Cl>[CH2:9]([NH:8][C:6]([C:5]1[CH:4]=[CH:3][C:2]([NH:1][C:20](=[N:1][C:2]2[CH:3]=[CH:4][C:5]([C:6](=[O:7])[NH:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])=[CH:17][CH:18]=2)[C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)=[CH:18][CH:17]=1)=[O:7])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]참가 물질
4
실험 절차
N,N'-Bis(4-n-octylcarbamylphenyl)benzamidine (4) was prepared from 4-amino-N-n-octylbenzamide and α,α,α-trichlorotoluene; pale-yellow oil: 1H-NMR (CDCl3) 7.7-6.9 (m, 14H), 6.2 (br t, 2H, J=6 Hz), 3.3 (br q, 4H, J=6 Hz), 1.7-0.7 (m, 30H); IR (CHCl3) 3430, 1640, 1590; MS (m/e) 582 (M+), 335 (base).
출처 및 근거
- ORD 기록