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Formaldehyde → Melamine formaldehyde

HRID 1088592
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인쇄 미리보기

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HRID 1088592 반응식
[OH-].[Na+].C(OCCCCCCCCCCCC)(=O)C1C=C(O)C(O)=[C:6]([OH:7])C=1.C(OC(C1C=CC=CC=1)C(=O)C1C=CC=CC=1)C.[N:45]1[C:52]([NH2:53])=[N:51][C:49]([NH2:50])=[N:48][C:46]=1[NH2:47].C=O>O>[CH2:6]=[O:7].[N:45]1[C:52]([NH2:53])=[N:51][C:49]([NH2:50])=[N:48][C:46]=1[NH2:47]
참가 물질반응 조건실험 절차출처 및 근거반응 노트

참가 물질

7

반응물 5

HCID 712FormaldehydeHCID 7955MelamineHCID 14425Dodecyl GallateHCID 14798Sodium Hydroxide2회HCID 101778Benzoin ethyl ether

생성물 1

HCID 93374Melamine formaldehyde

시약·촉매·용매 1

HCID 962
Water
용매

반응 조건

온도
60 °C

실험 절차

To 100 parts of an aqueous solution of pH 4.0 containing 5% of a styrene-maleic anhydride copolymer and a small amount of sodium hydroxide was added a mixed solution consisting of 10 parts of dodecyl gallate, 30 parts of a polyoxypropylene glycol monoether, 0.3 part of benzoin ethyl ether and 59.7 parts of an epoxy acrylate type photocurable resin (brand name: RIPOXY, manufactured by Showa Highpolymer Co., Ltd.), and they were emulsified. 10 parts of melamine, 25 parts of a 37% aqueous formaldehyde solution and 65 parts of water were adjusted to pH 9 with sodium hydroxide and then heated to 60° C. In 15 minutes, the mixture became transparent and a melamine-formaldehyde precondensate was obtained. This precondensate was added to the emulsion prepared previously. The resulting mixture was continuously stirred at 60° C. The formation of microcapsules was confirmed in 30 minutes and the microcapsule fluid was cooled to room temperature.

출처 및 근거

ORD 기록
ord-6805994fe59045298bc36e284a3c45c7
출처 데이터셋
uspto-grants-1990_10
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04963457

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