Styrene → Phenethyldimethylethoxysilane

HRID 1107613

반응식

HRID 1107613 반응식
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH3:9][SiH:10]([CH3:14])[O:11][CH2:12][CH3:13]>[Pt].C1(C)C=CC=CC=1>[CH2:1]([Si:10]([CH3:14])([CH3:9])[O:11][CH2:12][CH3:13])[CH2:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

참가 물질

5

반응물 2

HCID 7501Styrene3회HCID 61772Ethoxydimethylsilane2회

생성물 1

HCID 54188620Phenethyldimethylethoxysilane수율 27%

시약·촉매·용매 2

HCID 23939Platinum촉매HCID 1140Toluene용매

반응 조건

온도
41 °C

실험 절차

Comparative Example 1. (Reaction between Styrene and Dimethylethoxysilane) A glass tube was filled with 312 mg of styrene and 312 mg of dimethylethoxysilane. The contents were combined with 1 μL of a toluene solution of a complex of divinylsiloxane and 0-valence platinum (platinum content: 0.4 Wt. %). The tube was sealed with Teflon tape and was heated for 30 minutes in an oil bath at 41° C. After cooling, the product was subjected to GC analysis. The analyses confirmed that the conversion of styrene was 36% and that phenethyldimethylethoxysilane was produced at a yield of 27%. The yield of (α-methylbenzyl)dimethylethoxysilane was 8.5%.

후처리

  1. temperatureAfter cooling

출처 및 근거

ORD 기록
ord-bb1ecc69861a4a45b877fa71c023ca0c
출처 데이터셋
uspto-grants-2000_05
특허 번호
US06060620

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